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Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - An Ongoing Futuristic Career of Metal–Organic Frameworks and Ionic Liquids, A Magical Gateway to Capture CO2; A Critical Review
AU - Ali, Syed Awais
AU - Khan, Asmat Ullah
AU - Mulk, Waqad Ul
AU - Khan, Haris
AU - Nasir Shah, Syed
AU - Zahid, Afrah
AU - Habib, Khairul
AU - Shah, Mansoor Ul Hassan
AU - Othman, Mohd Hafiz Dzarfan
AU - Rahman, Saidur
PY - 2023/10/19
Y1 - 2023/10/19
N2 - Carbon capture and storage (CCS) technologies are the “knight in shining armor” that can save humanity from burnout in the longer term, minimizing damage from CO2 emissions by keeping them out of the atmosphere. Metal–organic frameworks (MOFs) have received a promising career for CO2 capture due to their high porosity, surface area, excellent metal-to-ligand interaction, and good affinity to capture CO2 molecules. On the other hand, Ionic liquids (ILs) as emerging solvents have reported a significant influence on CO2 solubility due to their wide range of tunability in the selection of a variety of cations and anions along with the advantage of nonvolatility, high thermal stability, and nonflammability. The current Review highlights the recent progress and ongoing careers of employing MOFs and ILs in carbon capture technologies before their commercialization on a large scale. A brief overview of CO2 capturing using MOFs and ILs is given under the influence of their possible functionalization to enhance their CO2 separation. Information on the possible integration of MOFs-ILs as a composite system or membrane-based gas separation is also presented in detail. The integration has a high potential to capture CO2 while minimizing the unit operation costs for a stable, efficient, and smooth industrial gas separation operation. Present work attempts to link the chemistry of MOF and IL and their successful hybridization (MOF-IL composite) to process the economics for CO2 capture.
AB - Carbon capture and storage (CCS) technologies are the “knight in shining armor” that can save humanity from burnout in the longer term, minimizing damage from CO2 emissions by keeping them out of the atmosphere. Metal–organic frameworks (MOFs) have received a promising career for CO2 capture due to their high porosity, surface area, excellent metal-to-ligand interaction, and good affinity to capture CO2 molecules. On the other hand, Ionic liquids (ILs) as emerging solvents have reported a significant influence on CO2 solubility due to their wide range of tunability in the selection of a variety of cations and anions along with the advantage of nonvolatility, high thermal stability, and nonflammability. The current Review highlights the recent progress and ongoing careers of employing MOFs and ILs in carbon capture technologies before their commercialization on a large scale. A brief overview of CO2 capturing using MOFs and ILs is given under the influence of their possible functionalization to enhance their CO2 separation. Information on the possible integration of MOFs-ILs as a composite system or membrane-based gas separation is also presented in detail. The integration has a high potential to capture CO2 while minimizing the unit operation costs for a stable, efficient, and smooth industrial gas separation operation. Present work attempts to link the chemistry of MOF and IL and their successful hybridization (MOF-IL composite) to process the economics for CO2 capture.
KW - Energy Engineering and Power Technology
KW - Fuel Technology
KW - General Chemical Engineering
U2 - 10.1021/acs.energyfuels.3c02377
DO - 10.1021/acs.energyfuels.3c02377
M3 - Journal article
VL - 37
SP - 15394
EP - 15428
JO - Energy and Fuels
JF - Energy and Fuels
SN - 0887-0624
IS - 20
ER -