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    Rights statement: This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Physical Chemistry B (Soft Condensed Matter and Biophysical Chemistry), copyright © 2020 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/acs.jpcb.0c04850

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Artificial Synthesis of Conjugated Microporous Polymers via Sonogashira-Hagihara Coupling

Research output: Contribution to Journal/MagazineJournal articlepeer-review

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Artificial Synthesis of Conjugated Microporous Polymers via Sonogashira-Hagihara Coupling. / Thomas, J.M.H.; Mollart, C.; Turner, L. et al.
In: Journal of Physical Chemistry B (Soft Condensed Matter and Biophysical Chemistry), Vol. 124, No. 33, 20.08.2020, p. 7318-7326.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

Harvard

Thomas, JMH, Mollart, C, Turner, L, Heasman, P, Fayon, P & Trewin, A 2020, 'Artificial Synthesis of Conjugated Microporous Polymers via Sonogashira-Hagihara Coupling', Journal of Physical Chemistry B (Soft Condensed Matter and Biophysical Chemistry), vol. 124, no. 33, pp. 7318-7326. https://doi.org/10.1021/acs.jpcb.0c04850

APA

Thomas, J. M. H., Mollart, C., Turner, L., Heasman, P., Fayon, P., & Trewin, A. (2020). Artificial Synthesis of Conjugated Microporous Polymers via Sonogashira-Hagihara Coupling. Journal of Physical Chemistry B (Soft Condensed Matter and Biophysical Chemistry), 124(33), 7318-7326. https://doi.org/10.1021/acs.jpcb.0c04850

Vancouver

Thomas JMH, Mollart C, Turner L, Heasman P, Fayon P, Trewin A. Artificial Synthesis of Conjugated Microporous Polymers via Sonogashira-Hagihara Coupling. Journal of Physical Chemistry B (Soft Condensed Matter and Biophysical Chemistry). 2020 Aug 20;124(33):7318-7326. Epub 2020 Jul 28. doi: 10.1021/acs.jpcb.0c04850

Author

Thomas, J.M.H. ; Mollart, C. ; Turner, L. et al. / Artificial Synthesis of Conjugated Microporous Polymers via Sonogashira-Hagihara Coupling. In: Journal of Physical Chemistry B (Soft Condensed Matter and Biophysical Chemistry). 2020 ; Vol. 124, No. 33. pp. 7318-7326.

Bibtex

@article{66171fca609445bc9ec62c131d260554,
title = "Artificial Synthesis of Conjugated Microporous Polymers via Sonogashira-Hagihara Coupling",
abstract = "Amorphous network materials are becoming increasingly important with applications, for example, as supercapacitors, battery anodes, and proton conduction membranes. The design of these materials is hampered by the amorphous nature of the structure and sensitivity to synthetic conditions. Here, we show that through artificial synthesis, fully mimicking the catalytic formation cycle, and full synthetic conditions, we can generate structural models that can fully describe the physical properties of these amorphous network materials. This opens up pathways for the rational design where complex structural influences, such as the solvent and catalyst choice, can be taken into account.",
author = "J.M.H. Thomas and C. Mollart and L. Turner and P. Heasman and P. Fayon and A. Trewin",
note = "This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Physical Chemistry B (Soft Condensed Matter and Biophysical Chemistry), copyright {\textcopyright} 2020 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/acs.jpcb.0c04850",
year = "2020",
month = aug,
day = "20",
doi = "10.1021/acs.jpcb.0c04850",
language = "English",
volume = "124",
pages = "7318--7326",
journal = "Journal of Physical Chemistry B (Soft Condensed Matter and Biophysical Chemistry)",
number = "33",

}

RIS

TY - JOUR

T1 - Artificial Synthesis of Conjugated Microporous Polymers via Sonogashira-Hagihara Coupling

AU - Thomas, J.M.H.

AU - Mollart, C.

AU - Turner, L.

AU - Heasman, P.

AU - Fayon, P.

AU - Trewin, A.

N1 - This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Physical Chemistry B (Soft Condensed Matter and Biophysical Chemistry), copyright © 2020 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/acs.jpcb.0c04850

PY - 2020/8/20

Y1 - 2020/8/20

N2 - Amorphous network materials are becoming increasingly important with applications, for example, as supercapacitors, battery anodes, and proton conduction membranes. The design of these materials is hampered by the amorphous nature of the structure and sensitivity to synthetic conditions. Here, we show that through artificial synthesis, fully mimicking the catalytic formation cycle, and full synthetic conditions, we can generate structural models that can fully describe the physical properties of these amorphous network materials. This opens up pathways for the rational design where complex structural influences, such as the solvent and catalyst choice, can be taken into account.

AB - Amorphous network materials are becoming increasingly important with applications, for example, as supercapacitors, battery anodes, and proton conduction membranes. The design of these materials is hampered by the amorphous nature of the structure and sensitivity to synthetic conditions. Here, we show that through artificial synthesis, fully mimicking the catalytic formation cycle, and full synthetic conditions, we can generate structural models that can fully describe the physical properties of these amorphous network materials. This opens up pathways for the rational design where complex structural influences, such as the solvent and catalyst choice, can be taken into account.

U2 - 10.1021/acs.jpcb.0c04850

DO - 10.1021/acs.jpcb.0c04850

M3 - Journal article

VL - 124

SP - 7318

EP - 7326

JO - Journal of Physical Chemistry B (Soft Condensed Matter and Biophysical Chemistry)

JF - Journal of Physical Chemistry B (Soft Condensed Matter and Biophysical Chemistry)

IS - 33

ER -