Rights statement: This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Physical Chemistry B (Soft Condensed Matter and Biophysical Chemistry), copyright © 2020 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/acs.jpcb.0c04850
Accepted author manuscript, 1.44 MB, PDF document
Available under license: CC BY-NC: Creative Commons Attribution-NonCommercial 4.0 International License
Final published version
Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
}
TY - JOUR
T1 - Artificial Synthesis of Conjugated Microporous Polymers via Sonogashira-Hagihara Coupling
AU - Thomas, J.M.H.
AU - Mollart, C.
AU - Turner, L.
AU - Heasman, P.
AU - Fayon, P.
AU - Trewin, A.
N1 - This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Physical Chemistry B (Soft Condensed Matter and Biophysical Chemistry), copyright © 2020 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/acs.jpcb.0c04850
PY - 2020/8/20
Y1 - 2020/8/20
N2 - Amorphous network materials are becoming increasingly important with applications, for example, as supercapacitors, battery anodes, and proton conduction membranes. The design of these materials is hampered by the amorphous nature of the structure and sensitivity to synthetic conditions. Here, we show that through artificial synthesis, fully mimicking the catalytic formation cycle, and full synthetic conditions, we can generate structural models that can fully describe the physical properties of these amorphous network materials. This opens up pathways for the rational design where complex structural influences, such as the solvent and catalyst choice, can be taken into account.
AB - Amorphous network materials are becoming increasingly important with applications, for example, as supercapacitors, battery anodes, and proton conduction membranes. The design of these materials is hampered by the amorphous nature of the structure and sensitivity to synthetic conditions. Here, we show that through artificial synthesis, fully mimicking the catalytic formation cycle, and full synthetic conditions, we can generate structural models that can fully describe the physical properties of these amorphous network materials. This opens up pathways for the rational design where complex structural influences, such as the solvent and catalyst choice, can be taken into account.
U2 - 10.1021/acs.jpcb.0c04850
DO - 10.1021/acs.jpcb.0c04850
M3 - Journal article
VL - 124
SP - 7318
EP - 7326
JO - Journal of Physical Chemistry B (Soft Condensed Matter and Biophysical Chemistry)
JF - Journal of Physical Chemistry B (Soft Condensed Matter and Biophysical Chemistry)
IS - 33
ER -