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Calculation of the effect of collisional broadening on high-resolution translational energy loss spectra: Special Issue: In honour of John H. Beynon

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Calculation of the effect of collisional broadening on high-resolution translational energy loss spectra: Special Issue: In honour of John H. Beynon. / Brenton, A.G; Jonathan, P.
In: International Journal of Mass Spectrometry, Vol. 230, No. 2, 01.12.2003, p. 185-192.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

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Brenton AG, Jonathan P. Calculation of the effect of collisional broadening on high-resolution translational energy loss spectra: Special Issue: In honour of John H. Beynon. International Journal of Mass Spectrometry. 2003 Dec 1;230(2):185-192. doi: 10.1016/j.ijms.2003.09.009

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@article{96b4b37ec06a4d7dbc1189c700fb1742,
title = "Calculation of the effect of collisional broadening on high-resolution translational energy loss spectra: Special Issue: In honour of John H. Beynon",
abstract = "The collisional broadening of peaks in the spectra arising from translational energy spectroscopy (TES) studies is theoretically investigated. A numerical calculation, based on the TRIO matrix ion-beam transport computer programme, is used to simulate the collision event and its effects on the focussing properties of a number of {\textquoteleft}double-focussing{\textquoteright} instrument designs. The ion-optical models utilised include a commercial mass spectrometer and two novel high-resolution energy spectrometers (TESI and TESII), incorporating quadrupole and hexapole field lenses to focus the beam and reduce image aberrations. For a given design of spectrometer, peak broadening is evaluated in terms of the translational energy change suffered by the ion during collision and the angle through which it is scattered.",
keywords = "Angle, Scattered, Collision",
author = "A.G Brenton and P Jonathan",
year = "2003",
month = dec,
day = "1",
doi = "10.1016/j.ijms.2003.09.009",
language = "English",
volume = "230",
pages = "185--192",
journal = "International Journal of Mass Spectrometry",
issn = "1387-3806",
publisher = "Elsevier",
number = "2",

}

RIS

TY - JOUR

T1 - Calculation of the effect of collisional broadening on high-resolution translational energy loss spectra

T2 - Special Issue: In honour of John H. Beynon

AU - Brenton, A.G

AU - Jonathan, P

PY - 2003/12/1

Y1 - 2003/12/1

N2 - The collisional broadening of peaks in the spectra arising from translational energy spectroscopy (TES) studies is theoretically investigated. A numerical calculation, based on the TRIO matrix ion-beam transport computer programme, is used to simulate the collision event and its effects on the focussing properties of a number of ‘double-focussing’ instrument designs. The ion-optical models utilised include a commercial mass spectrometer and two novel high-resolution energy spectrometers (TESI and TESII), incorporating quadrupole and hexapole field lenses to focus the beam and reduce image aberrations. For a given design of spectrometer, peak broadening is evaluated in terms of the translational energy change suffered by the ion during collision and the angle through which it is scattered.

AB - The collisional broadening of peaks in the spectra arising from translational energy spectroscopy (TES) studies is theoretically investigated. A numerical calculation, based on the TRIO matrix ion-beam transport computer programme, is used to simulate the collision event and its effects on the focussing properties of a number of ‘double-focussing’ instrument designs. The ion-optical models utilised include a commercial mass spectrometer and two novel high-resolution energy spectrometers (TESI and TESII), incorporating quadrupole and hexapole field lenses to focus the beam and reduce image aberrations. For a given design of spectrometer, peak broadening is evaluated in terms of the translational energy change suffered by the ion during collision and the angle through which it is scattered.

KW - Angle

KW - Scattered

KW - Collision

U2 - 10.1016/j.ijms.2003.09.009

DO - 10.1016/j.ijms.2003.09.009

M3 - Journal article

VL - 230

SP - 185

EP - 192

JO - International Journal of Mass Spectrometry

JF - International Journal of Mass Spectrometry

SN - 1387-3806

IS - 2

ER -