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Chlorinated very short-lived substances offset the long-term reduction of inorganic stratospheric chlorine

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  • Kimberlee Dubé
  • Susann Tegtmeier
  • Adam Bourassa
  • Johannes C. Laube
  • Andreas Engel
  • Laura N. Saunders
  • Kaley A. Walker
  • Ryan Hossaini
  • Ewa M. Bednarz
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Article number487
<mark>Journal publication date</mark>20/06/2025
<mark>Journal</mark>Communications Earth & Environment
Issue number1
Volume6
Publication StatusPublished
<mark>Original language</mark>English

Abstract

Over the past few decades, a reduction in chlorinated long-lived ozone-depleting substance emissions due to the regulations imposed by the Montreal Protocol has led to a global decrease in stratospheric chlorine. At the same time, emissions of chlorinated Very Short-Lived Substances, which are unregulated, have increased. Here we show that observed changes of inorganic stratospheric chlorine are inconsistent with changes in the tropospheric abundances of long-lived ozone-depleting substances. Satellite observations of stratospheric chlorine species from the Atmospheric Chemistry Experiment—Fourier Transform Spectrometer during 2004–2020 reveal that the observed decrease in inorganic stratospheric chlorine is 25%–30% smaller than expected based on trends of long-lived ozone-depleting substances alone. At mid-latitudes in the lower stratosphere, this can be explained by the chlorinated Very Short-Lived Substances increase, which offsets the long-term reduction of stratospheric chlorine by up to 30%.