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Clathrate and inclusion compounds : 12 : vibrational and NMR spectroscopic studies of carboxylic acid guests in Dianin's compound.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

Published
<mark>Journal publication date</mark>02/1997
<mark>Journal</mark>Journal of Inclusion Phenomena and Macrocyclic Chemistry
Issue number2
Volume27
Number of pages12
Pages (from-to)179-190
Publication StatusPublished
<mark>Original language</mark>English

Abstract

Infrared, Raman and solid state 13C-NMR spectra have been recorded for a range of clathrates of Dianin''s compound containing straight chain aliphatic carboxylic acids (formic - octanoic) as guests. The IR, Raman and NMR spectra can be satisfactorily interpreted in terms of dimer (formic and acetic) and monomer (propionic - octanoic) occupation of the cavities. The clathrates containing straight chain alcohol guests (methanol - octanol) have also been prepared to aid in the interpretation of the NMR data.