Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Clathrate and inclusion compounds : 12 : vibrational and NMR spectroscopic studies of carboxylic acid guests in Dianin's compound.
AU - Davies, J. Eric D.
AU - Tabner, Vivienne A.
PY - 1997/2
Y1 - 1997/2
N2 - Infrared, Raman and solid state 13C-NMR spectra have been recorded for a range of clathrates of Dianin''s compound containing straight chain aliphatic carboxylic acids (formic - octanoic) as guests. The IR, Raman and NMR spectra can be satisfactorily interpreted in terms of dimer (formic and acetic) and monomer (propionic - octanoic) occupation of the cavities. The clathrates containing straight chain alcohol guests (methanol - octanol) have also been prepared to aid in the interpretation of the NMR data.
AB - Infrared, Raman and solid state 13C-NMR spectra have been recorded for a range of clathrates of Dianin''s compound containing straight chain aliphatic carboxylic acids (formic - octanoic) as guests. The IR, Raman and NMR spectra can be satisfactorily interpreted in terms of dimer (formic and acetic) and monomer (propionic - octanoic) occupation of the cavities. The clathrates containing straight chain alcohol guests (methanol - octanol) have also been prepared to aid in the interpretation of the NMR data.
KW - IR spectroscopy - Raman spectroscopy - 13C-MAS NMR spectroscopy - Dianin''s compound - clathrates - carboxylic acids - alcohols
U2 - 10.1023/A:1007958323076
DO - 10.1023/A:1007958323076
M3 - Journal article
VL - 27
SP - 179
EP - 190
JO - Journal of Inclusion Phenomena and Macrocyclic Chemistry
JF - Journal of Inclusion Phenomena and Macrocyclic Chemistry
SN - 0923-0750
IS - 2
ER -