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Cloud-scale modelling of the impact of deep convection on the fate of oceanic bromoform in the troposphere: a case study over the west coast of Borneo

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Cloud-scale modelling of the impact of deep convection on the fate of oceanic bromoform in the troposphere : a case study over the west coast of Borneo. / Hamer, P. D.; Marécal, V.; Hossaini, R.; Pirre, M.; Krysztofiak, G.; Ziska, F.; Engel, A.; Sala, S.; Keber, T.; Bönisch, H.; Atlas, E.; Krüger, K.; Chipperfield, M.; Catoire, V.; Samah, A. A.; Dorf, M.; Siew Moi, P.; Schlager, H.; Pfeilsticker, K.

In: Atmospheric Chemistry and Physics, Vol. 21, No. 22, 23.11.2021, p. 16955-16984.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

Harvard

Hamer, PD, Marécal, V, Hossaini, R, Pirre, M, Krysztofiak, G, Ziska, F, Engel, A, Sala, S, Keber, T, Bönisch, H, Atlas, E, Krüger, K, Chipperfield, M, Catoire, V, Samah, AA, Dorf, M, Siew Moi, P, Schlager, H & Pfeilsticker, K 2021, 'Cloud-scale modelling of the impact of deep convection on the fate of oceanic bromoform in the troposphere: a case study over the west coast of Borneo', Atmospheric Chemistry and Physics, vol. 21, no. 22, pp. 16955-16984. https://doi.org/10.5194/acp-21-16955-2021

APA

Hamer, P. D., Marécal, V., Hossaini, R., Pirre, M., Krysztofiak, G., Ziska, F., Engel, A., Sala, S., Keber, T., Bönisch, H., Atlas, E., Krüger, K., Chipperfield, M., Catoire, V., Samah, A. A., Dorf, M., Siew Moi, P., Schlager, H., & Pfeilsticker, K. (2021). Cloud-scale modelling of the impact of deep convection on the fate of oceanic bromoform in the troposphere: a case study over the west coast of Borneo. Atmospheric Chemistry and Physics, 21(22), 16955-16984. https://doi.org/10.5194/acp-21-16955-2021

Vancouver

Author

Hamer, P. D. ; Marécal, V. ; Hossaini, R. ; Pirre, M. ; Krysztofiak, G. ; Ziska, F. ; Engel, A. ; Sala, S. ; Keber, T. ; Bönisch, H. ; Atlas, E. ; Krüger, K. ; Chipperfield, M. ; Catoire, V. ; Samah, A. A. ; Dorf, M. ; Siew Moi, P. ; Schlager, H. ; Pfeilsticker, K. / Cloud-scale modelling of the impact of deep convection on the fate of oceanic bromoform in the troposphere : a case study over the west coast of Borneo. In: Atmospheric Chemistry and Physics. 2021 ; Vol. 21, No. 22. pp. 16955-16984.

Bibtex

@article{38eb55c2ff004d42936e778eed4a3a26,
title = "Cloud-scale modelling of the impact of deep convection on the fate of oceanic bromoform in the troposphere: a case study over the west coast of Borneo",
abstract = "This paper presents a modelling study on the fate of CHBr3 and its product gases in the troposphere within the context of tropical deep convection. A cloud-scale case study was conducted along the west coast of Borneo, where several deep convective systems were triggered on the afternoon and early evening of 19 November 2011. These systems were sampled by the Falcon aircraft during the field campaign of the SHIVA project and analysed using a simulation with the cloud-resolving meteorological model C-CATT-BRAMS at 2×2 km resolution that represents the emissions, transport by large-scale flow, convection, photochemistry, and washout of CHBr3 and its product gases (PGs). We find that simulated CHBr3 mixing ratios and the observed values in the boundary layer and the outflow of the convective systems agree. However, the model underestimates the background CHBr3 mixing ratios in the upper troposphere, which suggests a missing source at the regional scale. An analysis of the simulated chemical speciation of bromine within and around each simulated convective system during the mature convective stage reveals that >85 % of the bromine derived from CHBr3 and its PGs is transported vertically to the point of convective detrainment in the form of CHBr3 and that the remaining small fraction is in the form of organic PGs, principally insoluble brominated carbonyls produced from the photo-oxidation of CHBr3. The model simulates that within the boundary layer and free troposphere, the inorganic PGs are only present in soluble forms, i.e. HBr, HOBr, and BrONO2, and, consequently, within the convective clouds, the inorganic PGs are almost entirely removed by wet scavenging. We find that HBr is the most abundant PG in background lower-tropospheric air and that this prevalence of HBr is a result of the relatively low background tropospheric ozone levels at the regional scale. Contrary to a previous study in a different environment, for the conditions in the simulation, the insoluble Br2 species is hardly formed within the convective systems and therefore plays no significant role in the vertical transport of bromine. This likely results from the relatively small quantities of simulated inorganic bromine involved, the presence of HBr in large excess compared to HOBr and BrO, and the relatively efficient removal of soluble compounds within the convective column.",
author = "Hamer, {P. D.} and V. Mar{\'e}cal and R. Hossaini and M. Pirre and G. Krysztofiak and F. Ziska and A. Engel and S. Sala and T. Keber and H. B{\"o}nisch and E. Atlas and K. Kr{\"u}ger and M. Chipperfield and V. Catoire and Samah, {A. A.} and M. Dorf and {Siew Moi}, P. and H. Schlager and K. Pfeilsticker",
year = "2021",
month = nov,
day = "23",
doi = "10.5194/acp-21-16955-2021",
language = "English",
volume = "21",
pages = "16955--16984",
journal = "Atmospheric Chemistry and Physics ",
issn = "1680-7316",
publisher = "Copernicus GmbH (Copernicus Publications) on behalf of the European Geosciences Union (EGU)",
number = "22",

}

RIS

TY - JOUR

T1 - Cloud-scale modelling of the impact of deep convection on the fate of oceanic bromoform in the troposphere

T2 - a case study over the west coast of Borneo

AU - Hamer, P. D.

AU - Marécal, V.

AU - Hossaini, R.

AU - Pirre, M.

AU - Krysztofiak, G.

AU - Ziska, F.

AU - Engel, A.

AU - Sala, S.

AU - Keber, T.

AU - Bönisch, H.

AU - Atlas, E.

AU - Krüger, K.

AU - Chipperfield, M.

AU - Catoire, V.

AU - Samah, A. A.

AU - Dorf, M.

AU - Siew Moi, P.

AU - Schlager, H.

AU - Pfeilsticker, K.

PY - 2021/11/23

Y1 - 2021/11/23

N2 - This paper presents a modelling study on the fate of CHBr3 and its product gases in the troposphere within the context of tropical deep convection. A cloud-scale case study was conducted along the west coast of Borneo, where several deep convective systems were triggered on the afternoon and early evening of 19 November 2011. These systems were sampled by the Falcon aircraft during the field campaign of the SHIVA project and analysed using a simulation with the cloud-resolving meteorological model C-CATT-BRAMS at 2×2 km resolution that represents the emissions, transport by large-scale flow, convection, photochemistry, and washout of CHBr3 and its product gases (PGs). We find that simulated CHBr3 mixing ratios and the observed values in the boundary layer and the outflow of the convective systems agree. However, the model underestimates the background CHBr3 mixing ratios in the upper troposphere, which suggests a missing source at the regional scale. An analysis of the simulated chemical speciation of bromine within and around each simulated convective system during the mature convective stage reveals that >85 % of the bromine derived from CHBr3 and its PGs is transported vertically to the point of convective detrainment in the form of CHBr3 and that the remaining small fraction is in the form of organic PGs, principally insoluble brominated carbonyls produced from the photo-oxidation of CHBr3. The model simulates that within the boundary layer and free troposphere, the inorganic PGs are only present in soluble forms, i.e. HBr, HOBr, and BrONO2, and, consequently, within the convective clouds, the inorganic PGs are almost entirely removed by wet scavenging. We find that HBr is the most abundant PG in background lower-tropospheric air and that this prevalence of HBr is a result of the relatively low background tropospheric ozone levels at the regional scale. Contrary to a previous study in a different environment, for the conditions in the simulation, the insoluble Br2 species is hardly formed within the convective systems and therefore plays no significant role in the vertical transport of bromine. This likely results from the relatively small quantities of simulated inorganic bromine involved, the presence of HBr in large excess compared to HOBr and BrO, and the relatively efficient removal of soluble compounds within the convective column.

AB - This paper presents a modelling study on the fate of CHBr3 and its product gases in the troposphere within the context of tropical deep convection. A cloud-scale case study was conducted along the west coast of Borneo, where several deep convective systems were triggered on the afternoon and early evening of 19 November 2011. These systems were sampled by the Falcon aircraft during the field campaign of the SHIVA project and analysed using a simulation with the cloud-resolving meteorological model C-CATT-BRAMS at 2×2 km resolution that represents the emissions, transport by large-scale flow, convection, photochemistry, and washout of CHBr3 and its product gases (PGs). We find that simulated CHBr3 mixing ratios and the observed values in the boundary layer and the outflow of the convective systems agree. However, the model underestimates the background CHBr3 mixing ratios in the upper troposphere, which suggests a missing source at the regional scale. An analysis of the simulated chemical speciation of bromine within and around each simulated convective system during the mature convective stage reveals that >85 % of the bromine derived from CHBr3 and its PGs is transported vertically to the point of convective detrainment in the form of CHBr3 and that the remaining small fraction is in the form of organic PGs, principally insoluble brominated carbonyls produced from the photo-oxidation of CHBr3. The model simulates that within the boundary layer and free troposphere, the inorganic PGs are only present in soluble forms, i.e. HBr, HOBr, and BrONO2, and, consequently, within the convective clouds, the inorganic PGs are almost entirely removed by wet scavenging. We find that HBr is the most abundant PG in background lower-tropospheric air and that this prevalence of HBr is a result of the relatively low background tropospheric ozone levels at the regional scale. Contrary to a previous study in a different environment, for the conditions in the simulation, the insoluble Br2 species is hardly formed within the convective systems and therefore plays no significant role in the vertical transport of bromine. This likely results from the relatively small quantities of simulated inorganic bromine involved, the presence of HBr in large excess compared to HOBr and BrO, and the relatively efficient removal of soluble compounds within the convective column.

U2 - 10.5194/acp-21-16955-2021

DO - 10.5194/acp-21-16955-2021

M3 - Journal article

VL - 21

SP - 16955

EP - 16984

JO - Atmospheric Chemistry and Physics

JF - Atmospheric Chemistry and Physics

SN - 1680-7316

IS - 22

ER -