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Cobalt-catalysed Markovnikov selective hydroboration of vinylarenes

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<mark>Journal publication date</mark>2017
<mark>Journal</mark>Chemical Communications
Issue number34
Volume53
Number of pages4
Pages (from-to)4726-4729
Publication StatusPublished
<mark>Original language</mark>English

Abstract

A bipyridiyl-oxazoline cobalt catalyst tBuBPOCoCl2 has been developed for the Markovnikov selective hydroboration of alkenes using pinacolborane and NaOtBu as the in situ activator with up to >98 : 2 branched : linear selectivity (24 examples, 45-92% isolated yield).