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Dichlorido(η6-p-cymene)[tris(2-cyanoethyl)phosphine]ruthenium(II)

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Dichlorido(η6-p-cymene)[tris(2-cyanoethyl)phosphine]ruthenium(II). / Henderson, William; Nair, Ashwin Gopalan; Halcovich, Nathan R. et al.
In: MolBank, Vol. 2018, No. 4, M1025, 12.10.2018.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Henderson, W, Nair, AG, Halcovich, NR & Tiekink, ERT 2018, 'Dichlorido(η6-p-cymene)[tris(2-cyanoethyl)phosphine]ruthenium(II)', MolBank, vol. 2018, no. 4, M1025. https://doi.org/10.3390/M1025

APA

Henderson, W., Nair, A. G., Halcovich, N. R., & Tiekink, E. R. T. (2018). Dichlorido(η6-p-cymene)[tris(2-cyanoethyl)phosphine]ruthenium(II). MolBank, 2018(4), Article M1025. https://doi.org/10.3390/M1025

Vancouver

Henderson W, Nair AG, Halcovich NR, Tiekink ERT. Dichlorido(η6-p-cymene)[tris(2-cyanoethyl)phosphine]ruthenium(II). MolBank. 2018 Oct 12;2018(4):M1025. doi: 10.3390/M1025

Author

Henderson, William ; Nair, Ashwin Gopalan ; Halcovich, Nathan R. et al. / Dichlorido(η6-p-cymene)[tris(2-cyanoethyl)phosphine]ruthenium(II). In: MolBank. 2018 ; Vol. 2018, No. 4.

Bibtex

@article{4c462f243d334d22a47440fd7a1fa595,
title = "Dichlorido(η6-p-cymene)[tris(2-cyanoethyl)phosphine]ruthenium(II)",
abstract = "The tris(2-cyanoethyl)phosphine (tcep) complex [RuCl2{P(CH2CH2CN)3}(η6-p-cymene)] (p-cymene = p-CH3C6H4 iPr) was synthesised by the bridge-splitting reaction of the chlorido-dimer [RuCl2(η6-p-cymene)]2with tcep. The complex was characterised by a single-crystal X-ray structure determination as well as NMR spectroscopy, ESI mass spectrometry, and microelemental analysis. X-ray crystallography shows the ruthenium atom is coordinated by p-cymene in a η6-fashion, two chlorides and the phosphorus atom of the tcep ligand with the donor set defining a distorted octahedral geometry. The ESI mass spectrometry study reveals that the complex readily forms negative ions [M + Cl]−and [2M + Cl]−by association with a chloride ion. {\textcopyright} 2018 by the authors. Licensee MDPI, Basel, Switzerland.",
keywords = "ESI mass spectrometry, P-cymene, Ruthenium, Tris(2-cyanoethyl)phosphine, X-ray crystallography",
author = "William Henderson and Nair, {Ashwin Gopalan} and Halcovich, {Nathan R.} and Tiekink, {Edward R. T.}",
year = "2018",
month = oct,
day = "12",
doi = "10.3390/M1025",
language = "English",
volume = "2018",
journal = "MolBank",
issn = "1422-8599",
publisher = "MDPI AG",
number = "4",

}

RIS

TY - JOUR

T1 - Dichlorido(η6-p-cymene)[tris(2-cyanoethyl)phosphine]ruthenium(II)

AU - Henderson, William

AU - Nair, Ashwin Gopalan

AU - Halcovich, Nathan R.

AU - Tiekink, Edward R. T.

PY - 2018/10/12

Y1 - 2018/10/12

N2 - The tris(2-cyanoethyl)phosphine (tcep) complex [RuCl2{P(CH2CH2CN)3}(η6-p-cymene)] (p-cymene = p-CH3C6H4 iPr) was synthesised by the bridge-splitting reaction of the chlorido-dimer [RuCl2(η6-p-cymene)]2with tcep. The complex was characterised by a single-crystal X-ray structure determination as well as NMR spectroscopy, ESI mass spectrometry, and microelemental analysis. X-ray crystallography shows the ruthenium atom is coordinated by p-cymene in a η6-fashion, two chlorides and the phosphorus atom of the tcep ligand with the donor set defining a distorted octahedral geometry. The ESI mass spectrometry study reveals that the complex readily forms negative ions [M + Cl]−and [2M + Cl]−by association with a chloride ion. © 2018 by the authors. Licensee MDPI, Basel, Switzerland.

AB - The tris(2-cyanoethyl)phosphine (tcep) complex [RuCl2{P(CH2CH2CN)3}(η6-p-cymene)] (p-cymene = p-CH3C6H4 iPr) was synthesised by the bridge-splitting reaction of the chlorido-dimer [RuCl2(η6-p-cymene)]2with tcep. The complex was characterised by a single-crystal X-ray structure determination as well as NMR spectroscopy, ESI mass spectrometry, and microelemental analysis. X-ray crystallography shows the ruthenium atom is coordinated by p-cymene in a η6-fashion, two chlorides and the phosphorus atom of the tcep ligand with the donor set defining a distorted octahedral geometry. The ESI mass spectrometry study reveals that the complex readily forms negative ions [M + Cl]−and [2M + Cl]−by association with a chloride ion. © 2018 by the authors. Licensee MDPI, Basel, Switzerland.

KW - ESI mass spectrometry

KW - P-cymene

KW - Ruthenium

KW - Tris(2-cyanoethyl)phosphine

KW - X-ray crystallography

U2 - 10.3390/M1025

DO - 10.3390/M1025

M3 - Journal article

VL - 2018

JO - MolBank

JF - MolBank

SN - 1422-8599

IS - 4

M1 - M1025

ER -