Home > Research > Publications & Outputs > Directing the H2-driven selective regeneration ...

Research

Electronic data

  • GC-COM-11-2021-004414_revised

    Accepted author manuscript, 2.23 MB, PDF document

    Available under license: CC BY-NC: Creative Commons Attribution-NonCommercial 4.0 International License

Links

Text available via DOI:

View graph of relations

Directing the H2-driven selective regeneration of NADH via Sn-doped Pt/SiO2

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Published

Standard

Directing the H2-driven selective regeneration of NADH via Sn-doped Pt/SiO2. / Burnett, Joseph; Li, Jianwei; McCue, Alan et al.
In: Green Chemistry, Vol. 24, No. 4, 21.02.2022, p. 1451-1455.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Burnett, J, Li, J, McCue, A, Kechagiopoulos, PN, Howe, RF & Wang, X 2022, 'Directing the H2-driven selective regeneration of NADH via Sn-doped Pt/SiO2', Green Chemistry, vol. 24, no. 4, pp. 1451-1455. https://doi.org/10.1039/D1GC04414A

APA

Burnett, J., Li, J., McCue, A., Kechagiopoulos, P. N., Howe, R. F., & Wang, X. (2022). Directing the H2-driven selective regeneration of NADH via Sn-doped Pt/SiO2. Green Chemistry, 24(4), 1451-1455. https://doi.org/10.1039/D1GC04414A

Vancouver

Burnett J, Li J, McCue A, Kechagiopoulos PN, Howe RF, Wang X. Directing the H2-driven selective regeneration of NADH via Sn-doped Pt/SiO2. Green Chemistry. 2022 Feb 21;24(4):1451-1455. Epub 2022 Jan 31. doi: 10.1039/D1GC04414A

Author

Burnett, Joseph ; Li, Jianwei ; McCue, Alan et al. / Directing the H2-driven selective regeneration of NADH via Sn-doped Pt/SiO2. In: Green Chemistry. 2022 ; Vol. 24, No. 4. pp. 1451-1455.

Bibtex

@article{6682c7b0f0a541ef80ec167a3e7dfc23,
title = "Directing the H2-driven selective regeneration of NADH via Sn-doped Pt/SiO2",
abstract = "H2-driven NADH regeneration has long suffered from low selectivity when non-enzymatic, particularly heterogeneous catalysts, are used. In addition to the unselective nature of the catalysts, the typically unmeasured NAD+ conversion has inevitably hindered catalyst development. Here we report Sn-doped Pt/SiO2 catalysts for the selective regeneration of NADH and show that doping Pt/SiO2 with 10 at.% Sn can deliver a selectivity of 90% (at ~100% conversion) using H2. We propose that this is a result of Sn disturbing the Pt ensemble, altering the mode of NAD+ adsorption and directing the reduction to the 1,4- position of the nicotinamide ring.",
author = "Joseph Burnett and Jianwei Li and Alan McCue and Kechagiopoulos, {Panagiotis N.} and Howe, {Russell F.} and Xiaodong Wang",
year = "2022",
month = feb,
day = "21",
doi = "10.1039/D1GC04414A",
language = "English",
volume = "24",
pages = "1451--1455",
journal = "Green Chemistry",
issn = "1463-9262",
publisher = "Royal Society of Chemistry",
number = "4",

}

RIS

TY - JOUR

T1 - Directing the H2-driven selective regeneration of NADH via Sn-doped Pt/SiO2

AU - Burnett, Joseph

AU - Li, Jianwei

AU - McCue, Alan

AU - Kechagiopoulos, Panagiotis N.

AU - Howe, Russell F.

AU - Wang, Xiaodong

PY - 2022/2/21

Y1 - 2022/2/21

N2 - H2-driven NADH regeneration has long suffered from low selectivity when non-enzymatic, particularly heterogeneous catalysts, are used. In addition to the unselective nature of the catalysts, the typically unmeasured NAD+ conversion has inevitably hindered catalyst development. Here we report Sn-doped Pt/SiO2 catalysts for the selective regeneration of NADH and show that doping Pt/SiO2 with 10 at.% Sn can deliver a selectivity of 90% (at ~100% conversion) using H2. We propose that this is a result of Sn disturbing the Pt ensemble, altering the mode of NAD+ adsorption and directing the reduction to the 1,4- position of the nicotinamide ring.

AB - H2-driven NADH regeneration has long suffered from low selectivity when non-enzymatic, particularly heterogeneous catalysts, are used. In addition to the unselective nature of the catalysts, the typically unmeasured NAD+ conversion has inevitably hindered catalyst development. Here we report Sn-doped Pt/SiO2 catalysts for the selective regeneration of NADH and show that doping Pt/SiO2 with 10 at.% Sn can deliver a selectivity of 90% (at ~100% conversion) using H2. We propose that this is a result of Sn disturbing the Pt ensemble, altering the mode of NAD+ adsorption and directing the reduction to the 1,4- position of the nicotinamide ring.

U2 - 10.1039/D1GC04414A

DO - 10.1039/D1GC04414A

M3 - Journal article

VL - 24

SP - 1451

EP - 1455

JO - Green Chemistry

JF - Green Chemistry

SN - 1463-9262

IS - 4

ER -