Final published version
Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
}
TY - JOUR
T1 - Electrochemical Properties and Electrode Reversibility Studies of Palm Shell Activated Carbon for Heavy Metal Removal
AU - Maarof, Hawaiah Imam
AU - Ajeel, Mohammed A.
AU - Daud, Wan Mohd Ashri Wan
AU - Aroua, Mohamed Kheireddine
PY - 2017/9/20
Y1 - 2017/9/20
N2 - The feasibility of palm shell activated carbon (PSAC) as an electrode for the purpose of wastewater treatment was studied for the first time using a common redox probe, Fe(CN)6 4−/Fe(CN)6 3− in 0.5 NaCl as the supporting electrolyte. Before the electrode reaction studies, the most suitable supporting electrolyte and the optimum percentage of carbon black (CB) was determined. This study reveals that the redox process was quasi-reversible while both PSAC electrodes with 20% and 30% CB showed a relatively low electron transfer resistance. A large background current due to capacitance was observed due to the porous characteristics of the PSAC electrode. A PSAC electrode with a 2 cm diameter was found to successfully remove 97% of Hg2+ from an initial concentration of 100 ppm after 3 hours of electrochemical treatment. Overall, this study proved that PSAC is a promising electrode material to remove metal ion from wastewater.
AB - The feasibility of palm shell activated carbon (PSAC) as an electrode for the purpose of wastewater treatment was studied for the first time using a common redox probe, Fe(CN)6 4−/Fe(CN)6 3− in 0.5 NaCl as the supporting electrolyte. Before the electrode reaction studies, the most suitable supporting electrolyte and the optimum percentage of carbon black (CB) was determined. This study reveals that the redox process was quasi-reversible while both PSAC electrodes with 20% and 30% CB showed a relatively low electron transfer resistance. A large background current due to capacitance was observed due to the porous characteristics of the PSAC electrode. A PSAC electrode with a 2 cm diameter was found to successfully remove 97% of Hg2+ from an initial concentration of 100 ppm after 3 hours of electrochemical treatment. Overall, this study proved that PSAC is a promising electrode material to remove metal ion from wastewater.
KW - activated carbon
KW - heavy metal
KW - mercury
KW - quasi-reversible
KW - reduction
U2 - 10.1016/j.electacta.2017.07.171
DO - 10.1016/j.electacta.2017.07.171
M3 - Journal article
AN - SCOPUS:85026840382
VL - 249
SP - 96
EP - 103
JO - Electrochimica Acta
JF - Electrochimica Acta
SN - 0013-4686
ER -