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Exploiting trifluoromethyl substituents for tuning orbital character of singlet and triplet states to increase the rate of thermally activated delayed fluorescence

Research output: Contribution to Journal/MagazineJournal articlepeer-review

Published
  • Jonathan S. Ward
  • Andrew Danos
  • Patrycja Stachelek
  • Mark A Fox
  • Andrei Batsanov
  • Andrew Monkman
  • Martin Bryce
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<mark>Journal publication date</mark>1/12/2020
<mark>Journal</mark>Materials Chemistry Frontiers
Issue number12
Volume4
Number of pages14
Pages (from-to)3602-3615
Publication StatusPublished
Early online date29/07/20
<mark>Original language</mark>English

Abstract

This work shows that trifluoromethyl (CF3) substituents can be used to increase the rate of thermally activated delayed fluorescence (TADF) in conjugated organic molecules by tuning the excitonic character of the singlet and triplet excited states.