Final published version
Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Fabrication of fluorine doped graphene and SmVO4 based dispersed and adsorptive photocatalyst for abatement of phenolic compounds from water and bacterial disinfection
AU - Shandilya, Pooja
AU - Mittal, Divya
AU - Soni, Mahesh
AU - Raizada, Pankaj
AU - Hosseini-Bandegharaei, Ahmad
AU - Saini, Adesh K.
AU - Singh, Pardeep
PY - 2018/12/1
Y1 - 2018/12/1
N2 - During heterogeneous photocatalysis, high dispersion of photocatalyst is vital for efficiency of slurry type photoreactors. In this work, we have prepared fluorine doped graphene (FG24) as a highly dispersible adsorbent by sonochemical exfoliation method. Moreover, SmVO4 (SV) nanoparticles were immobilized onto the surface of FG24 to prepare SV/FG24 photocatalyst, using post synthesis method. The zeta potential and Tyndall effect experiments confirmed the formation of highly dispersed SV/FG24 photocatalyst. The thickness of both FG24 and SV/FG24 was less than 2.0 nm. The band gap of SV/FG24 was 2.28 eV. The high surface area of SV/FG24 was suitable for adsorptive removal of phenol and 2, 4-dinitrophenol (DNP). The simultaneous process of adsorption and photocatalysis was the most effective for the degradation of selected phenolic compounds. Both phenol and DNP were mineralized in 10 h under visible light. The intermediates formation during the degradation process was proved by high-performance liquid chromatography and mass spectrometry analysis. The photocatalytic activity of SV/FG24 was also tested for photocatalytic bacterial disinfection of Escherichia coli, Bacillus subtilis, Pseudomonas fluorescence, Staphylococcus aureus, and Streptococcus enterica bacteria. The selected bacteria were deactivated using SV/FG24 in 3 h under visible light. Both OH˙ and O2˙¯ radicals played an important role during both degradation and disinfection process. Due to significant recyclability, SV/FG24 could be used as cost-effective photocatalyst for wastewater treatment. Unlike conventional slurry photo-reactors, no magnetic stirring was used during photocatalytic degradation reactions. We have successfully fabricated high-dispersed photocatalyst which remained dispersed for 10 h and effectively used for photocatalytic water purification process.
AB - During heterogeneous photocatalysis, high dispersion of photocatalyst is vital for efficiency of slurry type photoreactors. In this work, we have prepared fluorine doped graphene (FG24) as a highly dispersible adsorbent by sonochemical exfoliation method. Moreover, SmVO4 (SV) nanoparticles were immobilized onto the surface of FG24 to prepare SV/FG24 photocatalyst, using post synthesis method. The zeta potential and Tyndall effect experiments confirmed the formation of highly dispersed SV/FG24 photocatalyst. The thickness of both FG24 and SV/FG24 was less than 2.0 nm. The band gap of SV/FG24 was 2.28 eV. The high surface area of SV/FG24 was suitable for adsorptive removal of phenol and 2, 4-dinitrophenol (DNP). The simultaneous process of adsorption and photocatalysis was the most effective for the degradation of selected phenolic compounds. Both phenol and DNP were mineralized in 10 h under visible light. The intermediates formation during the degradation process was proved by high-performance liquid chromatography and mass spectrometry analysis. The photocatalytic activity of SV/FG24 was also tested for photocatalytic bacterial disinfection of Escherichia coli, Bacillus subtilis, Pseudomonas fluorescence, Staphylococcus aureus, and Streptococcus enterica bacteria. The selected bacteria were deactivated using SV/FG24 in 3 h under visible light. Both OH˙ and O2˙¯ radicals played an important role during both degradation and disinfection process. Due to significant recyclability, SV/FG24 could be used as cost-effective photocatalyst for wastewater treatment. Unlike conventional slurry photo-reactors, no magnetic stirring was used during photocatalytic degradation reactions. We have successfully fabricated high-dispersed photocatalyst which remained dispersed for 10 h and effectively used for photocatalytic water purification process.
KW - Fluorine doped graphene nanosheets
KW - SmVO
KW - Well-dispersed photocatalyst
KW - Photocatalytic water treatment
KW - Antibacterial activity
U2 - 10.1016/j.jclepro.2018.08.271
DO - 10.1016/j.jclepro.2018.08.271
M3 - Journal article
VL - 203
SP - 386
EP - 399
JO - Journal of Cleaner Production
JF - Journal of Cleaner Production
SN - 0959-6526
ER -