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Greener synthesis of 1,2-butylene carbonate from CO2 using graphene-inorganic nanocomposite catalyst

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Greener synthesis of 1,2-butylene carbonate from CO2 using graphene-inorganic nanocomposite catalyst. / Onyenkeadi, V; Kellici, Suela; Saha, B.
In: Energy, Vol. 165, No. Part A, 15.12.2018, p. 867-876.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Onyenkeadi, V, Kellici, S & Saha, B 2018, 'Greener synthesis of 1,2-butylene carbonate from CO2 using graphene-inorganic nanocomposite catalyst', Energy, vol. 165, no. Part A, pp. 867-876. https://doi.org/10.1016/j.energy.2018.09.135

APA

Onyenkeadi, V., Kellici, S., & Saha, B. (2018). Greener synthesis of 1,2-butylene carbonate from CO2 using graphene-inorganic nanocomposite catalyst. Energy, 165(Part A), 867-876. https://doi.org/10.1016/j.energy.2018.09.135

Vancouver

Onyenkeadi V, Kellici S, Saha B. Greener synthesis of 1,2-butylene carbonate from CO2 using graphene-inorganic nanocomposite catalyst. Energy. 2018 Dec 15;165(Part A):867-876. Epub 2018 Sept 20. doi: 10.1016/j.energy.2018.09.135

Author

Onyenkeadi, V ; Kellici, Suela ; Saha, B. / Greener synthesis of 1,2-butylene carbonate from CO2 using graphene-inorganic nanocomposite catalyst. In: Energy. 2018 ; Vol. 165, No. Part A. pp. 867-876.

Bibtex

@article{17104228bbf74ef6ad5af5df839650b9,
title = "Greener synthesis of 1,2-butylene carbonate from CO2 using graphene-inorganic nanocomposite catalyst",
abstract = "The synthesis of 1,2-butylene carbonate (BC) from cycloaddition reaction of 1,2-butylene oxide (BO) and carbon dioxide (CO2) was investigated using several heterogeneous catalysts in the absence of organic solvent. Continuous hydrothermal flow synthesis (CHFS) has been employed as a rapid and cleaner route for the synthesis of a highly efficient graphene-inorganic heterogeneous catalyst, ceria-lanthana-zirconia/graphene nanocomposite, represented as Ce–La–Zr/GO. The heterogeneous catalysts have been characterised using transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), X-ray powder diffraction (XRD) and nitrogen adsorption/desorption (BET for measuring the surface area/pore size distribution),. Ceria- lanthana-zirconia/graphene nanocomposite catalyst (Ce–La–Zr/GO) exhibited high catalytic activity as compared to other reported heterogeneous catalysts in the absence of any organic solvent with a selectivity of 76% and 64% yield of 1,2-butylene carbonate at the reaction conditions of 408 K, 75 bar in 20 h.",
author = "V Onyenkeadi and Suela Kellici and B Saha",
year = "2018",
month = dec,
day = "15",
doi = "10.1016/j.energy.2018.09.135",
language = "English",
volume = "165",
pages = "867--876",
journal = "Energy",
issn = "0360-5442",
publisher = "Elsevier Limited",
number = "Part A",

}

RIS

TY - JOUR

T1 - Greener synthesis of 1,2-butylene carbonate from CO2 using graphene-inorganic nanocomposite catalyst

AU - Onyenkeadi, V

AU - Kellici, Suela

AU - Saha, B

PY - 2018/12/15

Y1 - 2018/12/15

N2 - The synthesis of 1,2-butylene carbonate (BC) from cycloaddition reaction of 1,2-butylene oxide (BO) and carbon dioxide (CO2) was investigated using several heterogeneous catalysts in the absence of organic solvent. Continuous hydrothermal flow synthesis (CHFS) has been employed as a rapid and cleaner route for the synthesis of a highly efficient graphene-inorganic heterogeneous catalyst, ceria-lanthana-zirconia/graphene nanocomposite, represented as Ce–La–Zr/GO. The heterogeneous catalysts have been characterised using transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), X-ray powder diffraction (XRD) and nitrogen adsorption/desorption (BET for measuring the surface area/pore size distribution),. Ceria- lanthana-zirconia/graphene nanocomposite catalyst (Ce–La–Zr/GO) exhibited high catalytic activity as compared to other reported heterogeneous catalysts in the absence of any organic solvent with a selectivity of 76% and 64% yield of 1,2-butylene carbonate at the reaction conditions of 408 K, 75 bar in 20 h.

AB - The synthesis of 1,2-butylene carbonate (BC) from cycloaddition reaction of 1,2-butylene oxide (BO) and carbon dioxide (CO2) was investigated using several heterogeneous catalysts in the absence of organic solvent. Continuous hydrothermal flow synthesis (CHFS) has been employed as a rapid and cleaner route for the synthesis of a highly efficient graphene-inorganic heterogeneous catalyst, ceria-lanthana-zirconia/graphene nanocomposite, represented as Ce–La–Zr/GO. The heterogeneous catalysts have been characterised using transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), X-ray powder diffraction (XRD) and nitrogen adsorption/desorption (BET for measuring the surface area/pore size distribution),. Ceria- lanthana-zirconia/graphene nanocomposite catalyst (Ce–La–Zr/GO) exhibited high catalytic activity as compared to other reported heterogeneous catalysts in the absence of any organic solvent with a selectivity of 76% and 64% yield of 1,2-butylene carbonate at the reaction conditions of 408 K, 75 bar in 20 h.

U2 - 10.1016/j.energy.2018.09.135

DO - 10.1016/j.energy.2018.09.135

M3 - Journal article

VL - 165

SP - 867

EP - 876

JO - Energy

JF - Energy

SN - 0360-5442

IS - Part A

ER -