Final published version
Research output: Contribution to Journal/Magazine › Journal article › peer-review
<mark>Journal publication date</mark> | 20/04/2015 |
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<mark>Journal</mark> | Chemistry - A European Journal |
Issue number | 17 |
Volume | 21 |
Number of pages | 4 |
Pages (from-to) | 6358-6361 |
Publication Status | Published |
<mark>Original language</mark> | English |
Three isoskeletal tetranuclear coordination clusters with general formula [MII2DyIII2L4(EtOH)6](ClO4)2·2 EtOH, (M=Co, 1; M=Ni, 2) and [NiII2DyIII2L4Cl2(CH3CN)2]·2 CH3CN (3), have been synthesized and characterized. These air-stable compounds, and in particular 3, display efficient homogeneous catalytic behavior in the room-temperature synthesis of trans-4,5-diaminocyclopent-2-enones from 2-furaldehyde and primary or secondary amines under a non-inert atmosphere.