Final published version
Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
}
TY - JOUR
T1 - Heteronuclear 3 d/DyIII coordination clusters as catalysts in a domino reaction
AU - Griffiths, Kieran
AU - Gallop, Christopher W.D.
AU - Abdul-Sada, Alaa
AU - Vargas, Alfredo
AU - Navarro, Oscar
AU - Kostakis, George E.
PY - 2015/4/20
Y1 - 2015/4/20
N2 - Three isoskeletal tetranuclear coordination clusters with general formula [MII2DyIII2L4(EtOH)6](ClO4)2·2 EtOH, (M=Co, 1; M=Ni, 2) and [NiII2DyIII2L4Cl2(CH3CN)2]·2 CH3CN (3), have been synthesized and characterized. These air-stable compounds, and in particular 3, display efficient homogeneous catalytic behavior in the room-temperature synthesis of trans-4,5-diaminocyclopent-2-enones from 2-furaldehyde and primary or secondary amines under a non-inert atmosphere.
AB - Three isoskeletal tetranuclear coordination clusters with general formula [MII2DyIII2L4(EtOH)6](ClO4)2·2 EtOH, (M=Co, 1; M=Ni, 2) and [NiII2DyIII2L4Cl2(CH3CN)2]·2 CH3CN (3), have been synthesized and characterized. These air-stable compounds, and in particular 3, display efficient homogeneous catalytic behavior in the room-temperature synthesis of trans-4,5-diaminocyclopent-2-enones from 2-furaldehyde and primary or secondary amines under a non-inert atmosphere.
KW - amines
KW - coordination clusters
KW - domino reactions
KW - dysprosium
KW - homogeneous catalysis
U2 - 10.1002/chem.201500505
DO - 10.1002/chem.201500505
M3 - Journal article
AN - SCOPUS:84926644199
VL - 21
SP - 6358
EP - 6361
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
SN - 0947-6539
IS - 17
ER -