Home > Research > Publications & Outputs > Intermolecular artifacts in probe microscope im...

Research

Associated organisational unit

Links

Text available via DOI:

Keywords

View graph of relations

Intermolecular artifacts in probe microscope images of C-60 assemblies

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Published

Standard

Intermolecular artifacts in probe microscope images of C-60 assemblies. / Jarvis, Samuel Paul; Rashid, Mohammad Abdur; Sweetman, Adam et al.
In: Physical review B, Vol. 92, No. 24, 241405, 15.12.2015.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Jarvis, SP, Rashid, MA, Sweetman, A, Leaf, J, Taylor, S, Moriarty, P & Dunn, J 2015, 'Intermolecular artifacts in probe microscope images of C-60 assemblies', Physical review B, vol. 92, no. 24, 241405. https://doi.org/10.1103/PhysRevB.92.241405

APA

Jarvis, S. P., Rashid, M. A., Sweetman, A., Leaf, J., Taylor, S., Moriarty, P., & Dunn, J. (2015). Intermolecular artifacts in probe microscope images of C-60 assemblies. Physical review B, 92(24), Article 241405. https://doi.org/10.1103/PhysRevB.92.241405

Vancouver

Jarvis SP, Rashid MA, Sweetman A, Leaf J, Taylor S, Moriarty P et al. Intermolecular artifacts in probe microscope images of C-60 assemblies. Physical review B. 2015 Dec 15;92(24):241405. Epub 2015 Dec 9. doi: 10.1103/PhysRevB.92.241405

Author

Jarvis, Samuel Paul ; Rashid, Mohammad Abdur ; Sweetman, Adam et al. / Intermolecular artifacts in probe microscope images of C-60 assemblies. In: Physical review B. 2015 ; Vol. 92, No. 24.

Bibtex

@article{648b31a25f084c7aa19e514c813a7262,
title = "Intermolecular artifacts in probe microscope images of C-60 assemblies",
abstract = "Claims that dynamic force microscopy has the capability to resolve intermolecular bonds in real space continue to be vigorously debated. To date, studies have been restricted to planar molecular assemblies with small separations between neighboring molecules. Here we report the observation of intermolecular artifacts over much larger distances in 2D assemblies of C-60 molecules, with compelling evidence that in our case the tip apex is terminated by a C-60 molecule (rather than the CO termination typically exploited in ultrahigh resolution force microscopy). The complete absence of directional interactions such as hydrogen or halogen bonding, the nonplanar structure of C-60, and the fullerene termination of the tip apex in our case highlight that intermolecular artifacts are ubiquitous in dynamic force microscopy.",
keywords = "ATOMIC-FORCE MICROSCOPY, SUPRAMOLECULAR CHEMISTRY, MECHANICAL-PROPERTIES, SINGLE-MOLECULE, RESOLUTION, SURFACES, TIPS",
author = "Jarvis, {Samuel Paul} and Rashid, {Mohammad Abdur} and Adam Sweetman and Jeremy Leaf and Simon Taylor and Philip Moriarty and Janette Dunn",
year = "2015",
month = dec,
day = "15",
doi = "10.1103/PhysRevB.92.241405",
language = "English",
volume = "92",
journal = "Physical review B",
issn = "1098-0121",
publisher = "AMER PHYSICAL SOC",
number = "24",

}

RIS

TY - JOUR

T1 - Intermolecular artifacts in probe microscope images of C-60 assemblies

AU - Jarvis, Samuel Paul

AU - Rashid, Mohammad Abdur

AU - Sweetman, Adam

AU - Leaf, Jeremy

AU - Taylor, Simon

AU - Moriarty, Philip

AU - Dunn, Janette

PY - 2015/12/15

Y1 - 2015/12/15

N2 - Claims that dynamic force microscopy has the capability to resolve intermolecular bonds in real space continue to be vigorously debated. To date, studies have been restricted to planar molecular assemblies with small separations between neighboring molecules. Here we report the observation of intermolecular artifacts over much larger distances in 2D assemblies of C-60 molecules, with compelling evidence that in our case the tip apex is terminated by a C-60 molecule (rather than the CO termination typically exploited in ultrahigh resolution force microscopy). The complete absence of directional interactions such as hydrogen or halogen bonding, the nonplanar structure of C-60, and the fullerene termination of the tip apex in our case highlight that intermolecular artifacts are ubiquitous in dynamic force microscopy.

AB - Claims that dynamic force microscopy has the capability to resolve intermolecular bonds in real space continue to be vigorously debated. To date, studies have been restricted to planar molecular assemblies with small separations between neighboring molecules. Here we report the observation of intermolecular artifacts over much larger distances in 2D assemblies of C-60 molecules, with compelling evidence that in our case the tip apex is terminated by a C-60 molecule (rather than the CO termination typically exploited in ultrahigh resolution force microscopy). The complete absence of directional interactions such as hydrogen or halogen bonding, the nonplanar structure of C-60, and the fullerene termination of the tip apex in our case highlight that intermolecular artifacts are ubiquitous in dynamic force microscopy.

KW - ATOMIC-FORCE MICROSCOPY

KW - SUPRAMOLECULAR CHEMISTRY

KW - MECHANICAL-PROPERTIES

KW - SINGLE-MOLECULE

KW - RESOLUTION

KW - SURFACES

KW - TIPS

U2 - 10.1103/PhysRevB.92.241405

DO - 10.1103/PhysRevB.92.241405

M3 - Journal article

VL - 92

JO - Physical review B

JF - Physical review B

SN - 1098-0121

IS - 24

M1 - 241405

ER -