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Key advances in electrochemically-addressable single-molecule electronics

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Key advances in electrochemically-addressable single-molecule electronics. / Ward, Jonathan; Vezzoli, Andrea.
In: Current Opinion in Electrochemistry, Vol. 35, 101083, 31.10.2022.

Research output: Contribution to Journal/MagazineReview articlepeer-review

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Ward J, Vezzoli A. Key advances in electrochemically-addressable single-molecule electronics. Current Opinion in Electrochemistry. 2022 Oct 31;35:101083. Epub 2022 Jul 10. doi: 10.1016/j.coelec.2022.101083

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Ward, Jonathan ; Vezzoli, Andrea. / Key advances in electrochemically-addressable single-molecule electronics. In: Current Opinion in Electrochemistry. 2022 ; Vol. 35.

Bibtex

@article{f0e1f2cc8a3242adaf8a7336611a8c0d,
title = "Key advances in electrochemically-addressable single-molecule electronics",
abstract = "We discuss here recent advancements in the field of electrochemically-gated single-molecule conductance measurements. Important practical techniques and considerations are discussed alongside methods to determine the mechanism of charge transport in molecular junctions. Organic and organometallic systems are discussed, with a focus on systems showing clear electrochemically-gated activity. We highlight a clear need in the field for more in-depth analysis, at higher potential resolution and over a wider electrochemical window to provide more mechanistic insights in such systems. Detailed analyses are key to a deeper understanding of the physical processes operative in single-molecule junctions, and to translate fundamental studies into functional devices.",
keywords = "Molecular electronics, Molecular devices, Break-junction, Single-molecule electronics, Electrochemical gating, Charge transport mechanism",
author = "Jonathan Ward and Andrea Vezzoli",
year = "2022",
month = oct,
day = "31",
doi = "10.1016/j.coelec.2022.101083",
language = "English",
volume = "35",
journal = "Current Opinion in Electrochemistry",
issn = "2451-9103",
publisher = "Elsevier Science B.V.",

}

RIS

TY - JOUR

T1 - Key advances in electrochemically-addressable single-molecule electronics

AU - Ward, Jonathan

AU - Vezzoli, Andrea

PY - 2022/10/31

Y1 - 2022/10/31

N2 - We discuss here recent advancements in the field of electrochemically-gated single-molecule conductance measurements. Important practical techniques and considerations are discussed alongside methods to determine the mechanism of charge transport in molecular junctions. Organic and organometallic systems are discussed, with a focus on systems showing clear electrochemically-gated activity. We highlight a clear need in the field for more in-depth analysis, at higher potential resolution and over a wider electrochemical window to provide more mechanistic insights in such systems. Detailed analyses are key to a deeper understanding of the physical processes operative in single-molecule junctions, and to translate fundamental studies into functional devices.

AB - We discuss here recent advancements in the field of electrochemically-gated single-molecule conductance measurements. Important practical techniques and considerations are discussed alongside methods to determine the mechanism of charge transport in molecular junctions. Organic and organometallic systems are discussed, with a focus on systems showing clear electrochemically-gated activity. We highlight a clear need in the field for more in-depth analysis, at higher potential resolution and over a wider electrochemical window to provide more mechanistic insights in such systems. Detailed analyses are key to a deeper understanding of the physical processes operative in single-molecule junctions, and to translate fundamental studies into functional devices.

KW - Molecular electronics

KW - Molecular devices

KW - Break-junction

KW - Single-molecule electronics

KW - Electrochemical gating

KW - Charge transport mechanism

U2 - 10.1016/j.coelec.2022.101083

DO - 10.1016/j.coelec.2022.101083

M3 - Review article

VL - 35

JO - Current Opinion in Electrochemistry

JF - Current Opinion in Electrochemistry

SN - 2451-9103

M1 - 101083

ER -