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Manganese(I)-Catalyzed C-H Activation: The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Manganese(I)-Catalyzed C-H Activation: The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination. / Yahaya, NP; Appleby, KM; Teh, M et al.
In: Angewandte Chemie (International ed. in English), Vol. 55, No. 40, 26.09.2016, p. 12455-12459.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Yahaya, NP, Appleby, KM, Teh, M, Wagner, C, Troschke, E, Bray, JT, Duckett, SB, Hammarback, LA, Ward, JS, Milani, J, Pridmore, NE, Whitwood, AC, Lynam, JM & Fairlamb, IJ 2016, 'Manganese(I)-Catalyzed C-H Activation: The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination', Angewandte Chemie (International ed. in English), vol. 55, no. 40, pp. 12455-12459. https://doi.org/10.1002/anie.201606236

APA

Yahaya, NP., Appleby, KM., Teh, M., Wagner, C., Troschke, E., Bray, JT., Duckett, SB., Hammarback, LA., Ward, JS., Milani, J., Pridmore, NE., Whitwood, AC., Lynam, JM., & Fairlamb, IJ. (2016). Manganese(I)-Catalyzed C-H Activation: The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination. Angewandte Chemie (International ed. in English), 55(40), 12455-12459. https://doi.org/10.1002/anie.201606236

Vancouver

Yahaya NP, Appleby KM, Teh M, Wagner C, Troschke E, Bray JT et al. Manganese(I)-Catalyzed C-H Activation: The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination. Angewandte Chemie (International ed. in English). 2016 Sept 26;55(40):12455-12459. Epub 2016 Sept 7. doi: 10.1002/anie.201606236

Author

Yahaya, NP ; Appleby, KM ; Teh, M et al. / Manganese(I)-Catalyzed C-H Activation : The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination. In: Angewandte Chemie (International ed. in English). 2016 ; Vol. 55, No. 40. pp. 12455-12459.

Bibtex

@article{76bb67baf05a486186238d83c1a4d0cc,
title = "Manganese(I)-Catalyzed C-H Activation: The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination",
abstract = "Manganese-catalyzed C−H bond activation chemistry is emerging as a powerful and complementary method for molecular functionalization. A highly reactive seven-membered MnI intermediate is detected and characterized that is effective for H-transfer or reductive elimination to deliver alkenylated or pyridinium products, respectively. The two pathways are determined at MnI by judicious choice of an electron-deficient 2-pyrone substrate containing a 2-pyridyl directing group, which undergoes regioselective C−H bond activation, serving as a valuable system for probing the mechanistic features of Mn C−H bond activation chemistry.",
author = "NP Yahaya and KM Appleby and M Teh and C Wagner and E Troschke and JT Bray and SB Duckett and LA Hammarback and JS Ward and J Milani and NE Pridmore and AC Whitwood and JM Lynam and IJ Fairlamb",
year = "2016",
month = sep,
day = "26",
doi = "10.1002/anie.201606236",
language = "English",
volume = "55",
pages = "12455--12459",
journal = "Angewandte Chemie (International ed. in English)",
number = "40",

}

RIS

TY - JOUR

T1 - Manganese(I)-Catalyzed C-H Activation

T2 - The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination

AU - Yahaya, NP

AU - Appleby, KM

AU - Teh, M

AU - Wagner, C

AU - Troschke, E

AU - Bray, JT

AU - Duckett, SB

AU - Hammarback, LA

AU - Ward, JS

AU - Milani, J

AU - Pridmore, NE

AU - Whitwood, AC

AU - Lynam, JM

AU - Fairlamb, IJ

PY - 2016/9/26

Y1 - 2016/9/26

N2 - Manganese-catalyzed C−H bond activation chemistry is emerging as a powerful and complementary method for molecular functionalization. A highly reactive seven-membered MnI intermediate is detected and characterized that is effective for H-transfer or reductive elimination to deliver alkenylated or pyridinium products, respectively. The two pathways are determined at MnI by judicious choice of an electron-deficient 2-pyrone substrate containing a 2-pyridyl directing group, which undergoes regioselective C−H bond activation, serving as a valuable system for probing the mechanistic features of Mn C−H bond activation chemistry.

AB - Manganese-catalyzed C−H bond activation chemistry is emerging as a powerful and complementary method for molecular functionalization. A highly reactive seven-membered MnI intermediate is detected and characterized that is effective for H-transfer or reductive elimination to deliver alkenylated or pyridinium products, respectively. The two pathways are determined at MnI by judicious choice of an electron-deficient 2-pyrone substrate containing a 2-pyridyl directing group, which undergoes regioselective C−H bond activation, serving as a valuable system for probing the mechanistic features of Mn C−H bond activation chemistry.

U2 - 10.1002/anie.201606236

DO - 10.1002/anie.201606236

M3 - Journal article

C2 - 27603008

VL - 55

SP - 12455

EP - 12459

JO - Angewandte Chemie (International ed. in English)

JF - Angewandte Chemie (International ed. in English)

IS - 40

ER -