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MIDA–Vinylsilanes: Selective Cross-Couplings and Applications to the Synthesis of Functionalized Stilbenes

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<mark>Journal publication date</mark>2/01/2015
<mark>Journal</mark>Organic Letters
Issue number1
Volume17
Number of pages4
Pages (from-to)10-13
Publication StatusPublished
Early online date16/12/14
<mark>Original language</mark>English

Abstract

A rapid and stereodefined synthesis of MIDA–boryl vinylsilanes has been achieved through the hydrosilylation of an alkynylboronic ester. The E products which contain a silyl and boryl group can be selectively cross-coupled in a two-step bidirectional sequence to provide a rapid and high-yielding synthesis of complex styrenes.