Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - MIDA–Vinylsilanes
T2 - Selective Cross-Couplings and Applications to the Synthesis of Functionalized Stilbenes
AU - McLaughlin, Mark
AU - McAdam, C.A.
AU - Cook, Matthew J.
PY - 2015/1/2
Y1 - 2015/1/2
N2 - A rapid and stereodefined synthesis of MIDA–boryl vinylsilanes has been achieved through the hydrosilylation of an alkynylboronic ester. The E products which contain a silyl and boryl group can be selectively cross-coupled in a two-step bidirectional sequence to provide a rapid and high-yielding synthesis of complex styrenes.
AB - A rapid and stereodefined synthesis of MIDA–boryl vinylsilanes has been achieved through the hydrosilylation of an alkynylboronic ester. The E products which contain a silyl and boryl group can be selectively cross-coupled in a two-step bidirectional sequence to provide a rapid and high-yielding synthesis of complex styrenes.
U2 - 10.1021/ol503065a
DO - 10.1021/ol503065a
M3 - Journal article
VL - 17
SP - 10
EP - 13
JO - Organic Letters
JF - Organic Letters
SN - 1523-7060
IS - 1
ER -