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Nanoarchitecture factors of solid – electrolyte interphase formation via 3D nano-rheology microscopy and surface force-distance spectroscopy

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Nanoarchitecture factors of solid – electrolyte interphase formation via 3D nano-rheology microscopy and surface force-distance spectroscopy. / Chen, Yue; Wu, Wenkai; Gonzalez Munoz, Sergio et al.
In: Nature Communications, Vol. 14, 1321, 10.03.2023.

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@article{4c87ad7603bb4032a57313db994f2115,
title = "Nanoarchitecture factors of solid – electrolyte interphase formation via 3D nano-rheology microscopy and surface force-distance spectroscopy",
abstract = "The solid electrolyte interphase in rechargeable Li-ion batteries, its dynamics and, significantly, its nanoscale structure and composition, hold clues to high-performing and safe energy storage. Unfortunately, knowledge of solid electrolyte interphase formation is limited due to the lack of in situ nano-characterization tools for probing solid-liquid interfaces. Here, we link electrochemical atomic force microscopy, three-dimensional nano-rheology microscopy and surface force-distance spectroscopy, to study, in situ and operando, the dynamic formation of the solid electrolyte interphase starting from a few 0.1 nm thick electrical double layer to the full three-dimensional nanostructured solid electrolyte interphase on the typical graphite basal and edge planes in a Li-ion battery negative electrode. By probing the arrangement of solvent molecules and ions within the electric double layer and quantifying the three-dimensional mechanical property distribution of organic and inorganic components in the as-formed solid electrolyte interphase layer, we reveal the nanoarchitecture factors and atomistic picture of initial solid electrolyte interphase formation on graphite-based negative electrodes in strongly and weakly solvating electrolytes.",
keywords = "electrochemical analysis, Rechargeable batteries, batteries, SPM, scanning probe microscopy, atomic force microscopy, AFM, 3D Nanorheology, 3D electrochemical nanorheology, UFM ultrasonic force microscopy, electrical double layer",
author = "Yue Chen and Wenkai Wu and {Gonzalez Munoz}, Sergio and Leonardo Forcieri and Charlie Wells and Samuel Jarvis and Fangling Wu and Robert Young and Avishek Dey and Mark Isaaks and Mangayarkarasi Nagarathinam and Robert Palgrave and Nuria Tapia-Ruiz and Oleg Kolosov",
year = "2023",
month = mar,
day = "10",
doi = "10.1038/s41467-023-37033-7",
language = "English",
volume = "14",
journal = "Nature Communications",
issn = "2041-1723",
publisher = "Nature Publishing Group",

}

RIS

TY - JOUR

T1 - Nanoarchitecture factors of solid – electrolyte interphase formation via 3D nano-rheology microscopy and surface force-distance spectroscopy

AU - Chen, Yue

AU - Wu, Wenkai

AU - Gonzalez Munoz, Sergio

AU - Forcieri, Leonardo

AU - Wells, Charlie

AU - Jarvis, Samuel

AU - Wu, Fangling

AU - Young, Robert

AU - Dey, Avishek

AU - Isaaks, Mark

AU - Nagarathinam, Mangayarkarasi

AU - Palgrave, Robert

AU - Tapia-Ruiz, Nuria

AU - Kolosov, Oleg

PY - 2023/3/10

Y1 - 2023/3/10

N2 - The solid electrolyte interphase in rechargeable Li-ion batteries, its dynamics and, significantly, its nanoscale structure and composition, hold clues to high-performing and safe energy storage. Unfortunately, knowledge of solid electrolyte interphase formation is limited due to the lack of in situ nano-characterization tools for probing solid-liquid interfaces. Here, we link electrochemical atomic force microscopy, three-dimensional nano-rheology microscopy and surface force-distance spectroscopy, to study, in situ and operando, the dynamic formation of the solid electrolyte interphase starting from a few 0.1 nm thick electrical double layer to the full three-dimensional nanostructured solid electrolyte interphase on the typical graphite basal and edge planes in a Li-ion battery negative electrode. By probing the arrangement of solvent molecules and ions within the electric double layer and quantifying the three-dimensional mechanical property distribution of organic and inorganic components in the as-formed solid electrolyte interphase layer, we reveal the nanoarchitecture factors and atomistic picture of initial solid electrolyte interphase formation on graphite-based negative electrodes in strongly and weakly solvating electrolytes.

AB - The solid electrolyte interphase in rechargeable Li-ion batteries, its dynamics and, significantly, its nanoscale structure and composition, hold clues to high-performing and safe energy storage. Unfortunately, knowledge of solid electrolyte interphase formation is limited due to the lack of in situ nano-characterization tools for probing solid-liquid interfaces. Here, we link electrochemical atomic force microscopy, three-dimensional nano-rheology microscopy and surface force-distance spectroscopy, to study, in situ and operando, the dynamic formation of the solid electrolyte interphase starting from a few 0.1 nm thick electrical double layer to the full three-dimensional nanostructured solid electrolyte interphase on the typical graphite basal and edge planes in a Li-ion battery negative electrode. By probing the arrangement of solvent molecules and ions within the electric double layer and quantifying the three-dimensional mechanical property distribution of organic and inorganic components in the as-formed solid electrolyte interphase layer, we reveal the nanoarchitecture factors and atomistic picture of initial solid electrolyte interphase formation on graphite-based negative electrodes in strongly and weakly solvating electrolytes.

KW - electrochemical analysis

KW - Rechargeable batteries

KW - batteries

KW - SPM

KW - scanning probe microscopy

KW - atomic force microscopy

KW - AFM

KW - 3D Nanorheology

KW - 3D electrochemical nanorheology

KW - UFM ultrasonic force microscopy

KW - electrical double layer

U2 - 10.1038/s41467-023-37033-7

DO - 10.1038/s41467-023-37033-7

M3 - Journal article

VL - 14

JO - Nature Communications

JF - Nature Communications

SN - 2041-1723

M1 - 1321

ER -