Nucleophile induced ligand rearrangement reactions of alkoxy- and arylsilanes

Chemistry

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Nucleophile induced ligand rearrangement reactions of alkoxy- and arylsilanes. / Docherty, Jamie H.; Dominey, Andrew P.; Thomas, Stephen P.
In: Tetrahedron, Vol. 75, No. 24, 14.06.2019, p. 3330-3335.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Docherty, JH, Dominey, AP & Thomas, SP 2019, 'Nucleophile induced ligand rearrangement reactions of alkoxy- and arylsilanes', Tetrahedron, vol. 75, no. 24, pp. 3330-3335. https://doi.org/10.1016/j.tet.2019.04.062

APA

Docherty, J. H., Dominey, A. P., & Thomas, S. P. (2019). Nucleophile induced ligand rearrangement reactions of alkoxy- and arylsilanes. Tetrahedron, 75(24), 3330-3335. https://doi.org/10.1016/j.tet.2019.04.062

Vancouver

Docherty JH, Dominey AP, Thomas SP. Nucleophile induced ligand rearrangement reactions of alkoxy- and arylsilanes. Tetrahedron. 2019 Jun 14;75(24):3330-3335. doi: 10.1016/j.tet.2019.04.062

Author

Docherty, Jamie H. ; Dominey, Andrew P. ; Thomas, Stephen P. / Nucleophile induced ligand rearrangement reactions of alkoxy- and arylsilanes. In: Tetrahedron. 2019 ; Vol. 75, No. 24. pp. 3330-3335.

Bibtex

@article{97370be19f4b42f786741d9d66ecea56,

title = "Nucleophile induced ligand rearrangement reactions of alkoxy- and arylsilanes",

abstract = "The ligand-redistribution reactions of aryl- and alkoxy-hydrosilanes can potentially cause the formation of gaseous hydrosilanes, which are flammable and pyrophoric. The ability of generic nucleophiles to initiate the ligand-redistribution reaction of commonly used hydrosilane reagents was investigated, alongside methods to hinder and halt the formation of hazardous hydrosilanes. Our results show that the ligand-redistribution reaction can be completely inhibited by common electrophiles and first-row transition metal pre-catalysts.",

keywords = "Catalysis, Phenylsilane, Redistribution, Reduction, Silane",

author = "Docherty, {Jamie H.} and Dominey, {Andrew P.} and Thomas, {Stephen P.}",

year = "2019",

month = jun,

day = "14",

doi = "10.1016/j.tet.2019.04.062",

language = "English",

volume = "75",

pages = "3330--3335",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "Elsevier Limited",

number = "24",

}

RIS

TY - JOUR

T1 - Nucleophile induced ligand rearrangement reactions of alkoxy- and arylsilanes

AU - Docherty, Jamie H.

AU - Dominey, Andrew P.

AU - Thomas, Stephen P.

PY - 2019/6/14

Y1 - 2019/6/14

N2 - The ligand-redistribution reactions of aryl- and alkoxy-hydrosilanes can potentially cause the formation of gaseous hydrosilanes, which are flammable and pyrophoric. The ability of generic nucleophiles to initiate the ligand-redistribution reaction of commonly used hydrosilane reagents was investigated, alongside methods to hinder and halt the formation of hazardous hydrosilanes. Our results show that the ligand-redistribution reaction can be completely inhibited by common electrophiles and first-row transition metal pre-catalysts.

AB - The ligand-redistribution reactions of aryl- and alkoxy-hydrosilanes can potentially cause the formation of gaseous hydrosilanes, which are flammable and pyrophoric. The ability of generic nucleophiles to initiate the ligand-redistribution reaction of commonly used hydrosilane reagents was investigated, alongside methods to hinder and halt the formation of hazardous hydrosilanes. Our results show that the ligand-redistribution reaction can be completely inhibited by common electrophiles and first-row transition metal pre-catalysts.

KW - Catalysis

KW - Phenylsilane

KW - Redistribution

KW - Reduction

KW - Silane

UR - http://www.scopus.com/inward/record.url?scp=85065178314&partnerID=8YFLogxK

U2 - 10.1016/j.tet.2019.04.062

DO - 10.1016/j.tet.2019.04.062

M3 - Journal article

AN - SCOPUS:85065178314

VL - 75

SP - 3330

EP - 3335

JO - Tetrahedron

JF - Tetrahedron

SN - 0040-4020

IS - 24

ER -

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