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Octadienediyl dichlorides of ruthenium(IV) as synthetic reagents in organoruthenium chemistry; isolation of a protonated ‘open metallocene’ [Ru(5-C7H11)2H]BF4

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<mark>Journal publication date</mark>1988
<mark>Journal</mark>Chemical Communications
Issue number14
Number of pages3
Pages (from-to)951-953
Publication StatusPublished
<mark>Original language</mark>English

Abstract

Chloride extraction from [Ru(η3 : η3-C10H16)Cl2]2 or [Ru(η3 : η3-C10H16)Cl2L][L = P(OMe)3 or ButNC], in the presence of diolefins, results in labilisation of the 2,7-dimethyloctadienediyl ligand and provides syntheses of some new organoruthenium complexes, including the protonated ‘open metallocene’[Ru(η5-C7H11)2H][BF4].