Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Octadienediyl dichlorides of ruthenium(IV) as synthetic reagents in organoruthenium chemistry; isolation of a protonated ‘open metallocene’ [Ru(5-C7H11)2H]BF4
AU - Cox, David
AU - Roulet, Raymond
PY - 1988
Y1 - 1988
N2 - Chloride extraction from [Ru(η3 : η3-C10H16)Cl2]2 or [Ru(η3 : η3-C10H16)Cl2L][L = P(OMe)3 or ButNC], in the presence of diolefins, results in labilisation of the 2,7-dimethyloctadienediyl ligand and provides syntheses of some new organoruthenium complexes, including the protonated ‘open metallocene’[Ru(η5-C7H11)2H][BF4].
AB - Chloride extraction from [Ru(η3 : η3-C10H16)Cl2]2 or [Ru(η3 : η3-C10H16)Cl2L][L = P(OMe)3 or ButNC], in the presence of diolefins, results in labilisation of the 2,7-dimethyloctadienediyl ligand and provides syntheses of some new organoruthenium complexes, including the protonated ‘open metallocene’[Ru(η5-C7H11)2H][BF4].
U2 - 10.1039/c39880000951
DO - 10.1039/c39880000951
M3 - Journal article
SP - 951
EP - 953
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 14
ER -