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    Rights statement: This document is the Accepted Manuscript version of a Published Work that appeared in final form in Nano Letters, copyright ©2015 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/10.1021/acs.nanolett.5b03033

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Oligoyne molecular junctions for efficient room temperature thermoelectric power generation

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Oligoyne molecular junctions for efficient room temperature thermoelectric power generation. / Sadeghi, Hatef; Sangtarash, Sara; Lambert, Colin J.

In: Nano Letters, Vol. 15, No. 11, 12.10.2015, p. 7467-7472.

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@article{52ce9046a31b46c3ac33973660bad9f0,
title = "Oligoyne molecular junctions for efficient room temperature thermoelectric power generation",
abstract = "Understanding phonon transport at a molecular scale is fundamental to the development of high-performance thermoelectric materials for the conversion of waste heat into electricity. We have studied phonon and electron transport in alkane and oligoyne chains of various lengths and find that, due to the more rigid nature of the latter, the phonon thermal conductances of oligoynes are counterintuitively lower than that of the corresponding alkanes. The thermal conductance of oligoynes decreases monotonically with increasing length, whereas the thermal conductance of alkanes initially increases with length and then decreases. This difference in behavior arises from phonon filtering by the gold electrodes and disappears when higher-Debye-frequency electrodes are used. Consequently a molecule that better transmits higher-frequency phonon modes, combined with a low-Debye-frequency electrode that filters high-energy phonons is a viable strategy for suppressing phonon transmission through the molecular junctions. The low thermal conductance of oligoynes, combined with their higher thermopower and higher electrical conductance lead to a maximum thermoelectric figure of merit of ZT = 1.4, which is several orders of magnitude higher than that of alkanes.",
keywords = "Oligoynes, Alkynes, Alkanes, Thermal conductance, Thermoelectricity, Single molecule electronics",
author = "Hatef Sadeghi and Sara Sangtarash and Lambert, {Colin J.}",
note = "This document is the Accepted Manuscript version of a Published Work that appeared in final form in Nano Letters, copyright {\textcopyright}2015 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/10.1021/acs.nanolett.5b03033",
year = "2015",
month = oct,
day = "12",
doi = "10.1021/acs.nanolett.5b03033",
language = "English",
volume = "15",
pages = "7467--7472",
journal = "Nano Letters",
issn = "1530-6984",
publisher = "American Chemical Society",
number = "11",

}

RIS

TY - JOUR

T1 - Oligoyne molecular junctions for efficient room temperature thermoelectric power generation

AU - Sadeghi, Hatef

AU - Sangtarash, Sara

AU - Lambert, Colin J.

N1 - This document is the Accepted Manuscript version of a Published Work that appeared in final form in Nano Letters, copyright ©2015 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/10.1021/acs.nanolett.5b03033

PY - 2015/10/12

Y1 - 2015/10/12

N2 - Understanding phonon transport at a molecular scale is fundamental to the development of high-performance thermoelectric materials for the conversion of waste heat into electricity. We have studied phonon and electron transport in alkane and oligoyne chains of various lengths and find that, due to the more rigid nature of the latter, the phonon thermal conductances of oligoynes are counterintuitively lower than that of the corresponding alkanes. The thermal conductance of oligoynes decreases monotonically with increasing length, whereas the thermal conductance of alkanes initially increases with length and then decreases. This difference in behavior arises from phonon filtering by the gold electrodes and disappears when higher-Debye-frequency electrodes are used. Consequently a molecule that better transmits higher-frequency phonon modes, combined with a low-Debye-frequency electrode that filters high-energy phonons is a viable strategy for suppressing phonon transmission through the molecular junctions. The low thermal conductance of oligoynes, combined with their higher thermopower and higher electrical conductance lead to a maximum thermoelectric figure of merit of ZT = 1.4, which is several orders of magnitude higher than that of alkanes.

AB - Understanding phonon transport at a molecular scale is fundamental to the development of high-performance thermoelectric materials for the conversion of waste heat into electricity. We have studied phonon and electron transport in alkane and oligoyne chains of various lengths and find that, due to the more rigid nature of the latter, the phonon thermal conductances of oligoynes are counterintuitively lower than that of the corresponding alkanes. The thermal conductance of oligoynes decreases monotonically with increasing length, whereas the thermal conductance of alkanes initially increases with length and then decreases. This difference in behavior arises from phonon filtering by the gold electrodes and disappears when higher-Debye-frequency electrodes are used. Consequently a molecule that better transmits higher-frequency phonon modes, combined with a low-Debye-frequency electrode that filters high-energy phonons is a viable strategy for suppressing phonon transmission through the molecular junctions. The low thermal conductance of oligoynes, combined with their higher thermopower and higher electrical conductance lead to a maximum thermoelectric figure of merit of ZT = 1.4, which is several orders of magnitude higher than that of alkanes.

KW - Oligoynes

KW - Alkynes

KW - Alkanes

KW - Thermal conductance

KW - Thermoelectricity

KW - Single molecule electronics

U2 - 10.1021/acs.nanolett.5b03033

DO - 10.1021/acs.nanolett.5b03033

M3 - Journal article

C2 - 26458053

VL - 15

SP - 7467

EP - 7472

JO - Nano Letters

JF - Nano Letters

SN - 1530-6984

IS - 11

ER -