Final published version
Licence: CC BY: Creative Commons Attribution 4.0 International License
Research output: Contribution to Journal/Magazine › Journal article › peer-review
| <mark>Journal publication date</mark> | 23/05/2023 |
|---|---|
| <mark>Journal</mark> | Advanced Synthesis & Catalysis |
| Issue number | 10 |
| Volume | 365 |
| Number of pages | 5 |
| Pages (from-to) | 1602-1606 |
| Publication Status | Published |
| Early online date | 16/05/23 |
| <mark>Original language</mark> | English |
We present the first study on the application of platinum complexes in the hydrostannylation of terminal alkynes. A range of platinum complexes were screened, with PtCl 2/XPhos proving to provide the best selectivity for the β-(E)-vinyl stannane. The catalyst system is able to provide the corresponding vinyl stannane in selectivities which surpasses that which is typically afforded under palladium catalysis. Additionally, a telescoped hydrometallation/cross-coupling sequence has been developed, allowing for application of the vinyl stannanes without excessive manipulation or purification of the intermediate stannane. (Figure presented.).