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Probing Lewis Acid-Base Interactions in Single-Molecule Junctions

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<mark>Journal publication date</mark>2018
<mark>Journal</mark>Nanoscale
Issue number38
Volume10
Number of pages4
Pages (from-to)18131-18134
Publication StatusPublished
Early online date18/09/18
<mark>Original language</mark>English

Abstract

A novel strategy to regulate the tunneling mechanism for charge transport through an organoborane wire via Lewis acid-base interactions has been developed. A change from LUMO- to HOMO-dominated charge transport upon the addition of the fluoride is verified both experimentally and theoretically.