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    Rights statement: This is the author’s version of a work that was accepted for publication in Comptes Rendus Physique. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Comptes Rendus Physique, 17, 10, 2016 DOI: 10.1016/j.crhy.2016.08.003

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Quantum-interference-enhanced thermoelectricity in single molecules and molecular films

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Quantum-interference-enhanced thermoelectricity in single molecules and molecular films. / Lambert, Colin John; Sadeghi, Hatef; Al-Galiby, Qusiy.
In: Comptes Rendus Physique, Vol. 17, No. 10, 12.2016, p. 1084-1095.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

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Lambert CJ, Sadeghi H, Al-Galiby Q. Quantum-interference-enhanced thermoelectricity in single molecules and molecular films. Comptes Rendus Physique. 2016 Dec;17(10):1084-1095. Epub 2016 Aug 18. doi: 10.1016/j.crhy.2016.08.003

Author

Lambert, Colin John ; Sadeghi, Hatef ; Al-Galiby, Qusiy. / Quantum-interference-enhanced thermoelectricity in single molecules and molecular films. In: Comptes Rendus Physique. 2016 ; Vol. 17, No. 10. pp. 1084-1095.

Bibtex

@article{da5dcf95c9cb4e91b76e2738e36ecc9a,
title = "Quantum-interference-enhanced thermoelectricity in single molecules and molecular films",
abstract = "We provide a brief overview of recent measurements and predictions of thermoelectric properties of single-molecules and porous nanoribbons and discuss some principles underpinning strategies for enhancing their thermoelectric performance. The latter include (a) taking advantage of steep slopes in the electron transmission coefficient T(E)T(E), (b) creating structures with delta-function-like transmission coefficients and (c) utilising step-like features in T(E)T(E). To achieve high performance, we suggest that the latter may be the most fruitful, since it is less susceptible to inhomogeneous broadening. For the purpose of extrapolating thermoelectric properties of single or few molecules to monolayer molecular films, we also discuss the relevance of the conductance-weighted average Seebeck coefficient.",
keywords = "Molecular electronics, Thermoelectricity, Quantum interference, Seebeck coefficient",
author = "Lambert, {Colin John} and Hatef Sadeghi and Qusiy Al-Galiby",
note = "This is the author{\textquoteright}s version of a work that was accepted for publication in Comptes Rendus Physique. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Comptes Rendus Physique, 17, 10, 2016 DOI: 10.1016/j.crhy.2016.08.003",
year = "2016",
month = dec,
doi = "10.1016/j.crhy.2016.08.003",
language = "English",
volume = "17",
pages = "1084--1095",
journal = "Comptes Rendus Physique",
issn = "1631-0705",
publisher = "Elsevier Masson",
number = "10",

}

RIS

TY - JOUR

T1 - Quantum-interference-enhanced thermoelectricity in single molecules and molecular films

AU - Lambert, Colin John

AU - Sadeghi, Hatef

AU - Al-Galiby, Qusiy

N1 - This is the author’s version of a work that was accepted for publication in Comptes Rendus Physique. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Comptes Rendus Physique, 17, 10, 2016 DOI: 10.1016/j.crhy.2016.08.003

PY - 2016/12

Y1 - 2016/12

N2 - We provide a brief overview of recent measurements and predictions of thermoelectric properties of single-molecules and porous nanoribbons and discuss some principles underpinning strategies for enhancing their thermoelectric performance. The latter include (a) taking advantage of steep slopes in the electron transmission coefficient T(E)T(E), (b) creating structures with delta-function-like transmission coefficients and (c) utilising step-like features in T(E)T(E). To achieve high performance, we suggest that the latter may be the most fruitful, since it is less susceptible to inhomogeneous broadening. For the purpose of extrapolating thermoelectric properties of single or few molecules to monolayer molecular films, we also discuss the relevance of the conductance-weighted average Seebeck coefficient.

AB - We provide a brief overview of recent measurements and predictions of thermoelectric properties of single-molecules and porous nanoribbons and discuss some principles underpinning strategies for enhancing their thermoelectric performance. The latter include (a) taking advantage of steep slopes in the electron transmission coefficient T(E)T(E), (b) creating structures with delta-function-like transmission coefficients and (c) utilising step-like features in T(E)T(E). To achieve high performance, we suggest that the latter may be the most fruitful, since it is less susceptible to inhomogeneous broadening. For the purpose of extrapolating thermoelectric properties of single or few molecules to monolayer molecular films, we also discuss the relevance of the conductance-weighted average Seebeck coefficient.

KW - Molecular electronics

KW - Thermoelectricity

KW - Quantum interference

KW - Seebeck coefficient

U2 - 10.1016/j.crhy.2016.08.003

DO - 10.1016/j.crhy.2016.08.003

M3 - Journal article

VL - 17

SP - 1084

EP - 1095

JO - Comptes Rendus Physique

JF - Comptes Rendus Physique

SN - 1631-0705

IS - 10

ER -