Research output: Contribution to Journal/Magazine › Letter › peer-review
Research output: Contribution to Journal/Magazine › Letter › peer-review
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TY - JOUR
T1 - Sb-induced phase control of InAsSb nanowires grown by molecular beam epitaxy
AU - Zhuang, Qiandong
AU - Anyebe, Ezekiel
AU - Chen, R.
AU - Liu, H.
AU - Sanchez, Ana
AU - Rajpalke, Mohana K.
AU - Veal, Tim D.
AU - Wang, Z M
AU - huang, yongzheng
AU - Sun, H. D.
PY - 2015/1/5
Y1 - 2015/1/5
N2 - For the first time, we report a complete control of crystal structure in InAs1–xSbx NWs by tuning the antimony (Sb) composition. This claim is substantiated by high-resolution transmission electron microscopy combined with photoluminescence spectroscopy. The pure InAs nanowires generally show a mixture of wurtzite (WZ) and zinc-blende (ZB) phases, where addition of a small amount of Sb (∼2–4%) led to quasi-pure WZ InAsSb NWs, while further increase of Sb (∼10%) resulted in quasi-pure ZB InAsSb NWs. This phase transition is further evidenced by photoluminescence (PL) studies, where a dominant emission associated with the coexistence of WZ and ZB phases is present in the pure InAs NWs but absent in the PL spectrum of InAs0.96Sb0.04 NWs that instead shows a band-to-band emission. We also demonstrate that the Sb addition significantly reduces the stacking fault density in the NWs. This study provides new insights on the role of Sb addition for effective control of nanowire crystal structure.
AB - For the first time, we report a complete control of crystal structure in InAs1–xSbx NWs by tuning the antimony (Sb) composition. This claim is substantiated by high-resolution transmission electron microscopy combined with photoluminescence spectroscopy. The pure InAs nanowires generally show a mixture of wurtzite (WZ) and zinc-blende (ZB) phases, where addition of a small amount of Sb (∼2–4%) led to quasi-pure WZ InAsSb NWs, while further increase of Sb (∼10%) resulted in quasi-pure ZB InAsSb NWs. This phase transition is further evidenced by photoluminescence (PL) studies, where a dominant emission associated with the coexistence of WZ and ZB phases is present in the pure InAs NWs but absent in the PL spectrum of InAs0.96Sb0.04 NWs that instead shows a band-to-band emission. We also demonstrate that the Sb addition significantly reduces the stacking fault density in the NWs. This study provides new insights on the role of Sb addition for effective control of nanowire crystal structure.
KW - InAsSb
KW - nanowires
KW - phase
KW - molecular beam epitaxy
KW - TEM
KW - SEM
KW - photoluminescence
U2 - 10.1021/nl5040946
DO - 10.1021/nl5040946
M3 - Letter
VL - 15
SP - 1109
EP - 1116
JO - Nano Letters
JF - Nano Letters
SN - 1530-6984
IS - 2
ER -