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Secondary bonding in di-methyl-bis-(morpholine-4-carbodi-thio-ato-κ(2)S,S')tin(IV): crystal structure and Hirshfeld surface analysis

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Secondary bonding in di-methyl-bis-(morpholine-4-carbodi-thio-ato-κ(2)S,S')tin(IV): crystal structure and Hirshfeld surface analysis. / Zaldi, Nordiyana Binti; Hussen, Rusnah Syahila Duali; Lee, See Mun et al.
In: Acta crystallographica. Section E, Crystallographic communications, Vol. 73, No. 6, 01.06.2017, p. 842-848.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Zaldi, NB, Hussen, RSD, Lee, SM, Halcovitch, NR, Jotani, MM & Tiekink, ERT 2017, 'Secondary bonding in di-methyl-bis-(morpholine-4-carbodi-thio-ato-κ(2)S,S')tin(IV): crystal structure and Hirshfeld surface analysis', Acta crystallographica. Section E, Crystallographic communications, vol. 73, no. 6, pp. 842-848. https://doi.org/10.1107/S2056989017006855

APA

Zaldi, N. B., Hussen, R. S. D., Lee, S. M., Halcovitch, N. R., Jotani, M. M., & Tiekink, E. R. T. (2017). Secondary bonding in di-methyl-bis-(morpholine-4-carbodi-thio-ato-κ(2)S,S')tin(IV): crystal structure and Hirshfeld surface analysis. Acta crystallographica. Section E, Crystallographic communications, 73(6), 842-848. https://doi.org/10.1107/S2056989017006855

Vancouver

Zaldi NB, Hussen RSD, Lee SM, Halcovitch NR, Jotani MM, Tiekink ERT. Secondary bonding in di-methyl-bis-(morpholine-4-carbodi-thio-ato-κ(2)S,S')tin(IV): crystal structure and Hirshfeld surface analysis. Acta crystallographica. Section E, Crystallographic communications. 2017 Jun 1;73(6):842-848. doi: 10.1107/S2056989017006855

Author

Zaldi, Nordiyana Binti ; Hussen, Rusnah Syahila Duali ; Lee, See Mun et al. / Secondary bonding in di-methyl-bis-(morpholine-4-carbodi-thio-ato-κ(2)S,S')tin(IV) : crystal structure and Hirshfeld surface analysis. In: Acta crystallographica. Section E, Crystallographic communications. 2017 ; Vol. 73, No. 6. pp. 842-848.

Bibtex

@article{2939ce77b646434c899d73098f678a8e,
title = "Secondary bonding in di-methyl-bis-(morpholine-4-carbodi-thio-ato-κ(2)S,S')tin(IV): crystal structure and Hirshfeld surface analysis",
abstract = "The title compound, [Sn(CH3)2(C5H8NOS2)2], has the Sn(IV) atom bound by two methyl groups which lie over the weaker Sn-S bonds formed by two asymmetrically chelating di-thio-carbamate ligands so that the coordination geometry is skew-trapezoidal bipyramidal. The most prominent feature of the mol-ecular packing are secondary Sn⋯S inter-actions [Sn⋯S = 3.5654 (7) {\AA}] that lead to centrosymmetric dimers. These are connected into a three-dimensional architecture via methyl-ene-C-H⋯S and methyl-C-H⋯O(morpholino) inter-actions. The Sn⋯S inter-actions are clearly evident in the Hirshfeld surface analysis of the title compound along with a number of other inter-molecular contacts.",
keywords = "crystal structure, organotin, dithiocarbamate, tetrel bonding, Hirshfeld surface analysis",
author = "Zaldi, {Nordiyana Binti} and Hussen, {Rusnah Syahila Duali} and Lee, {See Mun} and Halcovitch, {Nathan R.} and Jotani, {Mukesh M.} and Tiekink, {Edward R. T.}",
year = "2017",
month = jun,
day = "1",
doi = "10.1107/S2056989017006855",
language = "English",
volume = "73",
pages = "842--848",
journal = "Acta crystallographica. Section E, Crystallographic communications",
issn = "2056-9890",
publisher = "International Union of Crystallography",
number = "6",

}

RIS

TY - JOUR

T1 - Secondary bonding in di-methyl-bis-(morpholine-4-carbodi-thio-ato-κ(2)S,S')tin(IV)

T2 - crystal structure and Hirshfeld surface analysis

AU - Zaldi, Nordiyana Binti

AU - Hussen, Rusnah Syahila Duali

AU - Lee, See Mun

AU - Halcovitch, Nathan R.

AU - Jotani, Mukesh M.

AU - Tiekink, Edward R. T.

PY - 2017/6/1

Y1 - 2017/6/1

N2 - The title compound, [Sn(CH3)2(C5H8NOS2)2], has the Sn(IV) atom bound by two methyl groups which lie over the weaker Sn-S bonds formed by two asymmetrically chelating di-thio-carbamate ligands so that the coordination geometry is skew-trapezoidal bipyramidal. The most prominent feature of the mol-ecular packing are secondary Sn⋯S inter-actions [Sn⋯S = 3.5654 (7) Å] that lead to centrosymmetric dimers. These are connected into a three-dimensional architecture via methyl-ene-C-H⋯S and methyl-C-H⋯O(morpholino) inter-actions. The Sn⋯S inter-actions are clearly evident in the Hirshfeld surface analysis of the title compound along with a number of other inter-molecular contacts.

AB - The title compound, [Sn(CH3)2(C5H8NOS2)2], has the Sn(IV) atom bound by two methyl groups which lie over the weaker Sn-S bonds formed by two asymmetrically chelating di-thio-carbamate ligands so that the coordination geometry is skew-trapezoidal bipyramidal. The most prominent feature of the mol-ecular packing are secondary Sn⋯S inter-actions [Sn⋯S = 3.5654 (7) Å] that lead to centrosymmetric dimers. These are connected into a three-dimensional architecture via methyl-ene-C-H⋯S and methyl-C-H⋯O(morpholino) inter-actions. The Sn⋯S inter-actions are clearly evident in the Hirshfeld surface analysis of the title compound along with a number of other inter-molecular contacts.

KW - crystal structure

KW - organotin

KW - dithiocarbamate

KW - tetrel bonding

KW - Hirshfeld surface analysis

U2 - 10.1107/S2056989017006855

DO - 10.1107/S2056989017006855

M3 - Journal article

C2 - 28638641

VL - 73

SP - 842

EP - 848

JO - Acta crystallographica. Section E, Crystallographic communications

JF - Acta crystallographica. Section E, Crystallographic communications

SN - 2056-9890

IS - 6

ER -