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Synthesis, characterization, and reactivity of a novel thallium arylspiroboronate ester

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Synthesis, characterization, and reactivity of a novel thallium arylspiroboronate ester. / Halcovitch, Nathan R.; Vogels, Christopher M.; Decken, Andreas et al.
In: Canadian Journal of Chemistry, Vol. 87, No. 1, 01.2009, p. 139-145.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Halcovitch, NR, Vogels, CM, Decken, A & Westcott, SA 2009, 'Synthesis, characterization, and reactivity of a novel thallium arylspiroboronate ester', Canadian Journal of Chemistry, vol. 87, no. 1, pp. 139-145. https://doi.org/10.1139/V08-107

APA

Halcovitch, N. R., Vogels, C. M., Decken, A., & Westcott, S. A. (2009). Synthesis, characterization, and reactivity of a novel thallium arylspiroboronate ester. Canadian Journal of Chemistry, 87(1), 139-145. https://doi.org/10.1139/V08-107

Vancouver

Halcovitch NR, Vogels CM, Decken A, Westcott SA. Synthesis, characterization, and reactivity of a novel thallium arylspiroboronate ester. Canadian Journal of Chemistry. 2009 Jan;87(1):139-145. doi: 10.1139/V08-107

Author

Halcovitch, Nathan R. ; Vogels, Christopher M. ; Decken, Andreas et al. / Synthesis, characterization, and reactivity of a novel thallium arylspiroboronate ester. In: Canadian Journal of Chemistry. 2009 ; Vol. 87, No. 1. pp. 139-145.

Bibtex

@article{4b00529c104d4fa1bae5741f7853f61e,
title = "Synthesis, characterization, and reactivity of a novel thallium arylspiroboronate ester",
abstract = "Addition of 3,5-di-tert-butylcatechol (butcat) to solutions of H 3B·SMe2 gave the novel diboron species B 2(butcat)3 (2) in moderate to high yields. Compound 2 reacts with Tl(acac) to give butcatB(acac) (4) and Tl(Bbutcat2) (5). Attempts to abstract the chlorides from [(dppb)Rh(μ-Cl)]2 (where dppb = 1,4-bis(diphenylphosphino)buthane) using 5 led to the unusual dimer [(dppb)Rh(μ-Cl)2(μ-Tl)Rh(dppb)][Bbutcat2] (6), which contains an unsymmetrical Rh-Tl-Rh bridge.",
keywords = "Arylspiroboronate ester, Non-coordinating anion, Rhodium, Thallium",
author = "Halcovitch, {Nathan R.} and Vogels, {Christopher M.} and Andreas Decken and Westcott, {Stephen A.}",
year = "2009",
month = jan,
doi = "10.1139/V08-107",
language = "English",
volume = "87",
pages = "139--145",
journal = "Canadian Journal of Chemistry",
issn = "0008-4042",
publisher = "National Research Council of Canada",
number = "1",

}

RIS

TY - JOUR

T1 - Synthesis, characterization, and reactivity of a novel thallium arylspiroboronate ester

AU - Halcovitch, Nathan R.

AU - Vogels, Christopher M.

AU - Decken, Andreas

AU - Westcott, Stephen A.

PY - 2009/1

Y1 - 2009/1

N2 - Addition of 3,5-di-tert-butylcatechol (butcat) to solutions of H 3B·SMe2 gave the novel diboron species B 2(butcat)3 (2) in moderate to high yields. Compound 2 reacts with Tl(acac) to give butcatB(acac) (4) and Tl(Bbutcat2) (5). Attempts to abstract the chlorides from [(dppb)Rh(μ-Cl)]2 (where dppb = 1,4-bis(diphenylphosphino)buthane) using 5 led to the unusual dimer [(dppb)Rh(μ-Cl)2(μ-Tl)Rh(dppb)][Bbutcat2] (6), which contains an unsymmetrical Rh-Tl-Rh bridge.

AB - Addition of 3,5-di-tert-butylcatechol (butcat) to solutions of H 3B·SMe2 gave the novel diboron species B 2(butcat)3 (2) in moderate to high yields. Compound 2 reacts with Tl(acac) to give butcatB(acac) (4) and Tl(Bbutcat2) (5). Attempts to abstract the chlorides from [(dppb)Rh(μ-Cl)]2 (where dppb = 1,4-bis(diphenylphosphino)buthane) using 5 led to the unusual dimer [(dppb)Rh(μ-Cl)2(μ-Tl)Rh(dppb)][Bbutcat2] (6), which contains an unsymmetrical Rh-Tl-Rh bridge.

KW - Arylspiroboronate ester

KW - Non-coordinating anion

KW - Rhodium

KW - Thallium

U2 - 10.1139/V08-107

DO - 10.1139/V08-107

M3 - Journal article

AN - SCOPUS:67650924601

VL - 87

SP - 139

EP - 145

JO - Canadian Journal of Chemistry

JF - Canadian Journal of Chemistry

SN - 0008-4042

IS - 1

ER -