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Synthesis of a dinuclear ferrocene-linked bis(phosphinoamide)scandium hydride complex

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Synthesis of a dinuclear ferrocene-linked bis(phosphinoamide)scandium hydride complex. / Halcovitch, Nathan R.; Fryzuk, Michael D.
In: Organometallics, Vol. 32, No. 20, 28.10.2013, p. 5705-5708.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Halcovitch, NR & Fryzuk, MD 2013, 'Synthesis of a dinuclear ferrocene-linked bis(phosphinoamide)scandium hydride complex', Organometallics, vol. 32, no. 20, pp. 5705-5708. https://doi.org/10.1021/om400353h

APA

Halcovitch, N. R., & Fryzuk, M. D. (2013). Synthesis of a dinuclear ferrocene-linked bis(phosphinoamide)scandium hydride complex. Organometallics, 32(20), 5705-5708. https://doi.org/10.1021/om400353h

Vancouver

Halcovitch NR, Fryzuk MD. Synthesis of a dinuclear ferrocene-linked bis(phosphinoamide)scandium hydride complex. Organometallics. 2013 Oct 28;32(20):5705-5708. Epub 2013 May 20. doi: 10.1021/om400353h

Author

Halcovitch, Nathan R. ; Fryzuk, Michael D. / Synthesis of a dinuclear ferrocene-linked bis(phosphinoamide)scandium hydride complex. In: Organometallics. 2013 ; Vol. 32, No. 20. pp. 5705-5708.

Bibtex

@article{0f57bced4eaa4e6f974507a4b7834da9,
title = "Synthesis of a dinuclear ferrocene-linked bis(phosphinoamide)scandium hydride complex",
abstract = "The ferrocene-based bis(phosphinoamide) fc(NHPiPr 2)2 (where fc = 1,1′-ferrocenyl) has been synthesized and coordinated to scandium via alkane elimination. The subsequent reaction of fc(NPiPr2)2ScCH 2SiMe3(THF) with H2 yields a dinuclear scandium hydride species wherein the scandium centers are bridged by both hydride and phosphinoamide fragments.",
author = "Halcovitch, {Nathan R.} and Fryzuk, {Michael D.}",
year = "2013",
month = oct,
day = "28",
doi = "10.1021/om400353h",
language = "English",
volume = "32",
pages = "5705--5708",
journal = "Organometallics",
issn = "0276-7333",
publisher = "American Chemical Society",
number = "20",

}

RIS

TY - JOUR

T1 - Synthesis of a dinuclear ferrocene-linked bis(phosphinoamide)scandium hydride complex

AU - Halcovitch, Nathan R.

AU - Fryzuk, Michael D.

PY - 2013/10/28

Y1 - 2013/10/28

N2 - The ferrocene-based bis(phosphinoamide) fc(NHPiPr 2)2 (where fc = 1,1′-ferrocenyl) has been synthesized and coordinated to scandium via alkane elimination. The subsequent reaction of fc(NPiPr2)2ScCH 2SiMe3(THF) with H2 yields a dinuclear scandium hydride species wherein the scandium centers are bridged by both hydride and phosphinoamide fragments.

AB - The ferrocene-based bis(phosphinoamide) fc(NHPiPr 2)2 (where fc = 1,1′-ferrocenyl) has been synthesized and coordinated to scandium via alkane elimination. The subsequent reaction of fc(NPiPr2)2ScCH 2SiMe3(THF) with H2 yields a dinuclear scandium hydride species wherein the scandium centers are bridged by both hydride and phosphinoamide fragments.

U2 - 10.1021/om400353h

DO - 10.1021/om400353h

M3 - Journal article

AN - SCOPUS:84887112105

VL - 32

SP - 5705

EP - 5708

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 20

ER -