Rights statement: This is the peer reviewed version of the following article:Zhang, S., Ma, S., Cao, B., Zhuang, Q., Xu, Y., Wang, J., Zhang, X., Nan, X., Hao, X., Xu, B., Angew. Chem. Int. Ed. 2023, 62, e202217127; Angew. Chem. 2023, 135, e202217127. which has been published in final form at https://onlinelibrary.wiley.com/doi/10.1002/anie.202217127 This article may be used for non-commercial purposes in accordance With Wiley Terms and Conditions for self-archiving.
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Final published version
Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
}
TY - JOUR
T1 - Synthesis of Fibrous Phosphorus Micropillar Arrays with Pyro‐Phototronic Effects
AU - Zhang, Shuai
AU - Ma, Shufang
AU - Cao, Ben
AU - Zhuang, Qiandong
AU - Xu, Yang
AU - Wang, Jiahui
AU - Zhang, Xishuo
AU - Nan, Xiaoye
AU - Hao, Xiaodong
AU - Xu, Bingshe
N1 - This is the peer reviewed version of the following article:Zhang, S., Ma, S., Cao, B., Zhuang, Q., Xu, Y., Wang, J., Zhang, X., Nan, X., Hao, X., Xu, B., Angew. Chem. Int. Ed. 2023, 62, e202217127; Angew. Chem. 2023, 135, e202217127. which has been published in final form at https://onlinelibrary.wiley.com/doi/10.1002/anie.202217127 This article may be used for non-commercial purposes in accordance With Wiley Terms and Conditions for self-archiving.
PY - 2023/1/23
Y1 - 2023/1/23
N2 - The bottom-up preparation of two-dimensional material micro-nano structures at scale facilitates the realisation of integrated applications in optoelectronic devices. Fibrous Phosphorus (FP), an allotrope of black phosphorus (BP), is one of the most promising candidate materials in the field of optoelectronics with its unique crystal structure and properties. [1] However, to date, there are no bottom-up micro-nano structure preparation methods for crystalline phosphorus allotropes. [1c, 2] Herein, we present the bottom-up preparation of fibrous phosphorus micropillar (FP-MP) arrays via a low-pressure gas-phase transport (LP-CVT) method that controls the directional phase transition from amorphous red phosphorus (ARP) to FP. In addition, self-powered photodetectors (PD) of FP-MP arrays with pyro-phototronic effects achieved detection beyond the band gap limit. Our results provide a new approach for bottom-up preparation of other crystalline allotropes of phosphorus.
AB - The bottom-up preparation of two-dimensional material micro-nano structures at scale facilitates the realisation of integrated applications in optoelectronic devices. Fibrous Phosphorus (FP), an allotrope of black phosphorus (BP), is one of the most promising candidate materials in the field of optoelectronics with its unique crystal structure and properties. [1] However, to date, there are no bottom-up micro-nano structure preparation methods for crystalline phosphorus allotropes. [1c, 2] Herein, we present the bottom-up preparation of fibrous phosphorus micropillar (FP-MP) arrays via a low-pressure gas-phase transport (LP-CVT) method that controls the directional phase transition from amorphous red phosphorus (ARP) to FP. In addition, self-powered photodetectors (PD) of FP-MP arrays with pyro-phototronic effects achieved detection beyond the band gap limit. Our results provide a new approach for bottom-up preparation of other crystalline allotropes of phosphorus.
KW - two-dimensional semiconductor material
KW - top-down synthesis
KW - fibrous phosphorus
KW - pyro-phototronic effect
KW - photodetectors
U2 - 10.1002/anie.202217127
DO - 10.1002/anie.202217127
M3 - Journal article
VL - 62
JO - Angewandte Chemie International Edition
JF - Angewandte Chemie International Edition
SN - 1433-7851
IS - 4
M1 - e202217127
ER -