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The interplay of thermally activated delayed fluorescence (TADF) and room temperature organic phosphorescence in sterically-constrained donor–acceptor charge-transfer molecules

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The interplay of thermally activated delayed fluorescence (TADF) and room temperature organic phosphorescence in sterically-constrained donor–acceptor charge-transfer molecules. / Ward, Jonathan S.; Nobuyasu, Roberto S.; Batsanov, Andrei S. et al.
In: Chemical Communications, Vol. 52, No. 12, 11.02.2016, p. 2612-2615.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

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Ward JS, Nobuyasu RS, Batsanov AS, Data P, Monkman AP, Dias FB et al. The interplay of thermally activated delayed fluorescence (TADF) and room temperature organic phosphorescence in sterically-constrained donor–acceptor charge-transfer molecules. Chemical Communications. 2016 Feb 11;52(12):2612-2615. Epub 2016 Jan 11. doi: 10.1039/c5cc09645f

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@article{69d3c97d47bb4032a421f4489f3d14fa,
title = "The interplay of thermally activated delayed fluorescence (TADF) and room temperature organic phosphorescence in sterically-constrained donor–acceptor charge-transfer molecules",
abstract = "A series of phenothiazine–dibenzothiophene-S,S-dioxide charge-transfer molecules have been synthesized. Increasing steric restriction around the donor–acceptor bond significantly alters contributions from TADF and phosphorescence. Bulky substituents on the 1-(and 9) position(s) of the phenothiazine result in no TADF in the solid state; instead strong phosphorescence is observed at ambient temperature.",
author = "Ward, {Jonathan S.} and Nobuyasu, {Roberto S.} and Batsanov, {Andrei S.} and Przemyslaw Data and Monkman, {Andrew P.} and Dias, {Fernando B.} and Bryce, {Martin R.}",
year = "2016",
month = feb,
day = "11",
doi = "10.1039/c5cc09645f",
language = "English",
volume = "52",
pages = "2612--2615",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "12",

}

RIS

TY - JOUR

T1 - The interplay of thermally activated delayed fluorescence (TADF) and room temperature organic phosphorescence in sterically-constrained donor–acceptor charge-transfer molecules

AU - Ward, Jonathan S.

AU - Nobuyasu, Roberto S.

AU - Batsanov, Andrei S.

AU - Data, Przemyslaw

AU - Monkman, Andrew P.

AU - Dias, Fernando B.

AU - Bryce, Martin R.

PY - 2016/2/11

Y1 - 2016/2/11

N2 - A series of phenothiazine–dibenzothiophene-S,S-dioxide charge-transfer molecules have been synthesized. Increasing steric restriction around the donor–acceptor bond significantly alters contributions from TADF and phosphorescence. Bulky substituents on the 1-(and 9) position(s) of the phenothiazine result in no TADF in the solid state; instead strong phosphorescence is observed at ambient temperature.

AB - A series of phenothiazine–dibenzothiophene-S,S-dioxide charge-transfer molecules have been synthesized. Increasing steric restriction around the donor–acceptor bond significantly alters contributions from TADF and phosphorescence. Bulky substituents on the 1-(and 9) position(s) of the phenothiazine result in no TADF in the solid state; instead strong phosphorescence is observed at ambient temperature.

U2 - 10.1039/c5cc09645f

DO - 10.1039/c5cc09645f

M3 - Journal article

VL - 52

SP - 2612

EP - 2615

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 12

ER -