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Toward synthesis and characterization of unconventional C-66 and C-68 fullerenes inside carbon nanotubes

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Toward synthesis and characterization of unconventional C-66 and C-68 fullerenes inside carbon nanotubes. / Zolyomi, Viktor; Peterlik, Herwig; Bernardi, Johannes et al.
In: The Journal of Physical Chemistry C, Vol. 118, No. 51, 26.12.2014, p. 30260-30268.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Zolyomi, V, Peterlik, H, Bernardi, J, Bokor, M, Laszlo, I, Koltai, J, Kuerti, J, Knupfer, M, Kuzmany, H, Pichler, T & Simon, F 2014, 'Toward synthesis and characterization of unconventional C-66 and C-68 fullerenes inside carbon nanotubes', The Journal of Physical Chemistry C, vol. 118, no. 51, pp. 30260-30268. https://doi.org/10.1021/jp509755x

APA

Zolyomi, V., Peterlik, H., Bernardi, J., Bokor, M., Laszlo, I., Koltai, J., Kuerti, J., Knupfer, M., Kuzmany, H., Pichler, T., & Simon, F. (2014). Toward synthesis and characterization of unconventional C-66 and C-68 fullerenes inside carbon nanotubes. The Journal of Physical Chemistry C, 118(51), 30260-30268. https://doi.org/10.1021/jp509755x

Vancouver

Zolyomi V, Peterlik H, Bernardi J, Bokor M, Laszlo I, Koltai J et al. Toward synthesis and characterization of unconventional C-66 and C-68 fullerenes inside carbon nanotubes. The Journal of Physical Chemistry C. 2014 Dec 26;118(51):30260-30268. Epub 2014 Nov 25. doi: 10.1021/jp509755x

Author

Zolyomi, Viktor ; Peterlik, Herwig ; Bernardi, Johannes et al. / Toward synthesis and characterization of unconventional C-66 and C-68 fullerenes inside carbon nanotubes. In: The Journal of Physical Chemistry C. 2014 ; Vol. 118, No. 51. pp. 30260-30268.

Bibtex

@article{124b70ec785143da8b753200f1925032,
title = "Toward synthesis and characterization of unconventional C-66 and C-68 fullerenes inside carbon nanotubes",
abstract = "We present compelling evidence pointing to the possible synthesis of unconventional C-66 and C-68 fullerenes in the interior of single-walled carbon nanotubes. The production proceeds from C(60)(-)toluene/benzene clathrates encapsulated inside the nanotubes using heat-driven nanotesttube chemistry. All isomers violate the so-called isolated pentagon rule and are stabilized solely by the proximity of the wall of the host nanotube. We present detailed characterization of the unconventional fullerenes using Raman spectroscopy, C-13 isotope labeling of the benzene molecules, transmission electron microscopy, X-ray diffractometry, and first-principles calculations. Multiple isomers of both C-66 and C-68 are identified in the sample. We argue that our method opens the way to high-yield synthesis of unconventional fullerenes.",
keywords = "ENCAPSULATED C-60, SINGLE, GROWTH, PEAPODS",
author = "Viktor Zolyomi and Herwig Peterlik and Johannes Bernardi and Monika Bokor and Istvan Laszlo and Janos Koltai and Jeno Kuerti and Martin Knupfer and Hans Kuzmany and Thomas Pichler and Ferenc Simon",
year = "2014",
month = dec,
day = "26",
doi = "10.1021/jp509755x",
language = "English",
volume = "118",
pages = "30260--30268",
journal = "The Journal of Physical Chemistry C",
issn = "1932-7447",
publisher = "American Chemical Society",
number = "51",

}

RIS

TY - JOUR

T1 - Toward synthesis and characterization of unconventional C-66 and C-68 fullerenes inside carbon nanotubes

AU - Zolyomi, Viktor

AU - Peterlik, Herwig

AU - Bernardi, Johannes

AU - Bokor, Monika

AU - Laszlo, Istvan

AU - Koltai, Janos

AU - Kuerti, Jeno

AU - Knupfer, Martin

AU - Kuzmany, Hans

AU - Pichler, Thomas

AU - Simon, Ferenc

PY - 2014/12/26

Y1 - 2014/12/26

N2 - We present compelling evidence pointing to the possible synthesis of unconventional C-66 and C-68 fullerenes in the interior of single-walled carbon nanotubes. The production proceeds from C(60)(-)toluene/benzene clathrates encapsulated inside the nanotubes using heat-driven nanotesttube chemistry. All isomers violate the so-called isolated pentagon rule and are stabilized solely by the proximity of the wall of the host nanotube. We present detailed characterization of the unconventional fullerenes using Raman spectroscopy, C-13 isotope labeling of the benzene molecules, transmission electron microscopy, X-ray diffractometry, and first-principles calculations. Multiple isomers of both C-66 and C-68 are identified in the sample. We argue that our method opens the way to high-yield synthesis of unconventional fullerenes.

AB - We present compelling evidence pointing to the possible synthesis of unconventional C-66 and C-68 fullerenes in the interior of single-walled carbon nanotubes. The production proceeds from C(60)(-)toluene/benzene clathrates encapsulated inside the nanotubes using heat-driven nanotesttube chemistry. All isomers violate the so-called isolated pentagon rule and are stabilized solely by the proximity of the wall of the host nanotube. We present detailed characterization of the unconventional fullerenes using Raman spectroscopy, C-13 isotope labeling of the benzene molecules, transmission electron microscopy, X-ray diffractometry, and first-principles calculations. Multiple isomers of both C-66 and C-68 are identified in the sample. We argue that our method opens the way to high-yield synthesis of unconventional fullerenes.

KW - ENCAPSULATED C-60

KW - SINGLE

KW - GROWTH

KW - PEAPODS

U2 - 10.1021/jp509755x

DO - 10.1021/jp509755x

M3 - Journal article

VL - 118

SP - 30260

EP - 30268

JO - The Journal of Physical Chemistry C

JF - The Journal of Physical Chemistry C

SN - 1932-7447

IS - 51

ER -