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Translational spectroscopy of the triatomic dications CO2+2, OCS2+ and CS2+2

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Translational spectroscopy of the triatomic dications CO2+2, OCS2+ and CS2+2. / Jonathan, P.; Hamdan, M.; Brenton, A.G. et al.
In: Chemical Physics Letters, Vol. 119, No. 1, 01.01.1988, p. 159-170.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Jonathan, P, Hamdan, M, Brenton, AG & Willett, GD 1988, 'Translational spectroscopy of the triatomic dications CO2+2, OCS2+ and CS2+2', Chemical Physics Letters, vol. 119, no. 1, pp. 159-170. https://doi.org/10.1016/0301-0104(88)80015-6

APA

Jonathan, P., Hamdan, M., Brenton, A. G., & Willett, G. D. (1988). Translational spectroscopy of the triatomic dications CO2+2, OCS2+ and CS2+2. Chemical Physics Letters, 119(1), 159-170. https://doi.org/10.1016/0301-0104(88)80015-6

Vancouver

Jonathan P, Hamdan M, Brenton AG, Willett GD. Translational spectroscopy of the triatomic dications CO2+2, OCS2+ and CS2+2. Chemical Physics Letters. 1988 Jan 1;119(1):159-170. doi: 10.1016/0301-0104(88)80015-6

Author

Jonathan, P. ; Hamdan, M. ; Brenton, A.G. et al. / Translational spectroscopy of the triatomic dications CO2+2, OCS2+ and CS2+2. In: Chemical Physics Letters. 1988 ; Vol. 119, No. 1. pp. 159-170.

Bibtex

@article{3aceb0d47be540dfb218f99f9310dbf0,
title = "Translational spectroscopy of the triatomic dications CO2+2, OCS2+ and CS2+2",
abstract = "Measurement of single-electron capture (SEC) and translational energy spectroscopy (TES) of the triatomic dications CO2+2, OCS2+, CS2+2 at high product ion resolution (typically 0.6 eV) is facilitated by a novel translational spectrometer. Calibration of SEC spectra allows the detection and precise assignment of observed state-selective processes; TES data indicate the presence of dication state having the same spin symmetry. Since single and double ionisation of each triatomic neutral ACB (where A and B represent O and S) to low-lying cation states occurs by removal of essentially non-bonding electrons, the bond lengths and energies of each ACB, ACB+ and ACB2+ are similar. Therefore, current data permit the evaluation of electronic levels of the triatomic dications in excellent agreement with previous experimental and theoretical work. A systematic procedure for future investigations of multiply charged molecular ions is proposed.",
author = "P. Jonathan and M. Hamdan and A.G. Brenton and G.D. Willett",
year = "1988",
month = jan,
day = "1",
doi = "10.1016/0301-0104(88)80015-6",
language = "English",
volume = "119",
pages = "159--170",
journal = "Chemical Physics Letters",
issn = "0301-0104",
publisher = "Elsevier",
number = "1",

}

RIS

TY - JOUR

T1 - Translational spectroscopy of the triatomic dications CO2+2, OCS2+ and CS2+2

AU - Jonathan, P.

AU - Hamdan, M.

AU - Brenton, A.G.

AU - Willett, G.D.

PY - 1988/1/1

Y1 - 1988/1/1

N2 - Measurement of single-electron capture (SEC) and translational energy spectroscopy (TES) of the triatomic dications CO2+2, OCS2+, CS2+2 at high product ion resolution (typically 0.6 eV) is facilitated by a novel translational spectrometer. Calibration of SEC spectra allows the detection and precise assignment of observed state-selective processes; TES data indicate the presence of dication state having the same spin symmetry. Since single and double ionisation of each triatomic neutral ACB (where A and B represent O and S) to low-lying cation states occurs by removal of essentially non-bonding electrons, the bond lengths and energies of each ACB, ACB+ and ACB2+ are similar. Therefore, current data permit the evaluation of electronic levels of the triatomic dications in excellent agreement with previous experimental and theoretical work. A systematic procedure for future investigations of multiply charged molecular ions is proposed.

AB - Measurement of single-electron capture (SEC) and translational energy spectroscopy (TES) of the triatomic dications CO2+2, OCS2+, CS2+2 at high product ion resolution (typically 0.6 eV) is facilitated by a novel translational spectrometer. Calibration of SEC spectra allows the detection and precise assignment of observed state-selective processes; TES data indicate the presence of dication state having the same spin symmetry. Since single and double ionisation of each triatomic neutral ACB (where A and B represent O and S) to low-lying cation states occurs by removal of essentially non-bonding electrons, the bond lengths and energies of each ACB, ACB+ and ACB2+ are similar. Therefore, current data permit the evaluation of electronic levels of the triatomic dications in excellent agreement with previous experimental and theoretical work. A systematic procedure for future investigations of multiply charged molecular ions is proposed.

U2 - 10.1016/0301-0104(88)80015-6

DO - 10.1016/0301-0104(88)80015-6

M3 - Journal article

VL - 119

SP - 159

EP - 170

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0301-0104

IS - 1

ER -