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Triarylamine polymers of bridged phenylenes by (N-heterocyclic carbene)-palladium catalysed C-N coupling

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Triarylamine polymers of bridged phenylenes by (N-heterocyclic carbene)-palladium catalysed C-N coupling. / Sprick, Reiner Sebastian; Hoyos, Mario; Morrison, John James et al.
In: Journal of Materials Chemistry C, Vol. 1, No. 20, 2013, p. 3327-3336.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Sprick, RS, Hoyos, M, Morrison, JJ, Grace, IM, Lambert, C, Navarro, O & Turner, ML 2013, 'Triarylamine polymers of bridged phenylenes by (N-heterocyclic carbene)-palladium catalysed C-N coupling', Journal of Materials Chemistry C, vol. 1, no. 20, pp. 3327-3336. https://doi.org/10.1039/c3tc30368c

APA

Sprick, R. S., Hoyos, M., Morrison, J. J., Grace, I. M., Lambert, C., Navarro, O., & Turner, M. L. (2013). Triarylamine polymers of bridged phenylenes by (N-heterocyclic carbene)-palladium catalysed C-N coupling. Journal of Materials Chemistry C, 1(20), 3327-3336. https://doi.org/10.1039/c3tc30368c

Vancouver

Sprick RS, Hoyos M, Morrison JJ, Grace IM, Lambert C, Navarro O et al. Triarylamine polymers of bridged phenylenes by (N-heterocyclic carbene)-palladium catalysed C-N coupling. Journal of Materials Chemistry C. 2013;1(20):3327-3336. doi: 10.1039/c3tc30368c

Author

Sprick, Reiner Sebastian ; Hoyos, Mario ; Morrison, John James et al. / Triarylamine polymers of bridged phenylenes by (N-heterocyclic carbene)-palladium catalysed C-N coupling. In: Journal of Materials Chemistry C. 2013 ; Vol. 1, No. 20. pp. 3327-3336.

Bibtex

@article{13a6f6a4fd0940fbb22c12dd6372c449,
title = "Triarylamine polymers of bridged phenylenes by (N-heterocyclic carbene)-palladium catalysed C-N coupling",
abstract = "A library of triarylamine copolymers with 2,7-fluorene, 3,7-dibenzo[b,d] thiophene and 2,7-carbazole units incorporated in the polymer backbone is reported. The polymers were synthesised by using C-N coupling of anilines and dibromoarenes, catalysed by N-heterocyclic carbene complexes of palladium. The properties of the polymers were tuned by changing the nature of the fused ring structure and the substitution of the pendant benzene of the arylamine. The use of these polymers as the charge transporting layer of an OFET is demonstrated with the highest mobility found for polymers derived from 2,7-dibromo-9,9'-dioctylfluorene and 4-methoxy-2-methylaniline.",
keywords = "FIELD-EFFECT TRANSISTORS, LIGHT-EMITTING-DIODES, COMPLEXES, POLY(TRIARYLAMINE)S, COPOLYMERS, AMINATION, MOBILITY, ACIDS",
author = "Sprick, {Reiner Sebastian} and Mario Hoyos and Morrison, {John James} and Grace, {Iain Mark} and Colin Lambert and Oscar Navarro and Turner, {Michael Lewis}",
year = "2013",
doi = "10.1039/c3tc30368c",
language = "English",
volume = "1",
pages = "3327--3336",
journal = "Journal of Materials Chemistry C",
issn = "2050-7526",
publisher = "Royal Society of Chemistry",
number = "20",

}

RIS

TY - JOUR

T1 - Triarylamine polymers of bridged phenylenes by (N-heterocyclic carbene)-palladium catalysed C-N coupling

AU - Sprick, Reiner Sebastian

AU - Hoyos, Mario

AU - Morrison, John James

AU - Grace, Iain Mark

AU - Lambert, Colin

AU - Navarro, Oscar

AU - Turner, Michael Lewis

PY - 2013

Y1 - 2013

N2 - A library of triarylamine copolymers with 2,7-fluorene, 3,7-dibenzo[b,d] thiophene and 2,7-carbazole units incorporated in the polymer backbone is reported. The polymers were synthesised by using C-N coupling of anilines and dibromoarenes, catalysed by N-heterocyclic carbene complexes of palladium. The properties of the polymers were tuned by changing the nature of the fused ring structure and the substitution of the pendant benzene of the arylamine. The use of these polymers as the charge transporting layer of an OFET is demonstrated with the highest mobility found for polymers derived from 2,7-dibromo-9,9'-dioctylfluorene and 4-methoxy-2-methylaniline.

AB - A library of triarylamine copolymers with 2,7-fluorene, 3,7-dibenzo[b,d] thiophene and 2,7-carbazole units incorporated in the polymer backbone is reported. The polymers were synthesised by using C-N coupling of anilines and dibromoarenes, catalysed by N-heterocyclic carbene complexes of palladium. The properties of the polymers were tuned by changing the nature of the fused ring structure and the substitution of the pendant benzene of the arylamine. The use of these polymers as the charge transporting layer of an OFET is demonstrated with the highest mobility found for polymers derived from 2,7-dibromo-9,9'-dioctylfluorene and 4-methoxy-2-methylaniline.

KW - FIELD-EFFECT TRANSISTORS

KW - LIGHT-EMITTING-DIODES

KW - COMPLEXES

KW - POLY(TRIARYLAMINE)S

KW - COPOLYMERS

KW - AMINATION

KW - MOBILITY

KW - ACIDS

U2 - 10.1039/c3tc30368c

DO - 10.1039/c3tc30368c

M3 - Journal article

VL - 1

SP - 3327

EP - 3336

JO - Journal of Materials Chemistry C

JF - Journal of Materials Chemistry C

SN - 2050-7526

IS - 20

ER -