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Vibrational spectroscopic investigations of M(Imidazole)2Ni(CN)4.2 Dioxane clathrates.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

  • Yüksel Tufan
  • Nurcan Karacan
  • J. Eric D. Davies
<mark>Journal publication date</mark>02/1999
<mark>Journal</mark>Journal of Inclusion Phenomena and Macrocyclic Chemistry
Issue number2
Number of pages6
Pages (from-to)149-154
Publication StatusPublished
<mark>Original language</mark>English


Four new clathrates of the formula M(Im)2Ni(CN)4·2·Dioxane (where M = Co, Ni, Cu, Cd; Im = Imidazole) have been prepared in powder form and their FT-IR and laser-Raman spectra are reported for the first time. These clathrates are analogues to the previously reported classical Hofmann type clathrates except for the copper clathrate. The Cu clathrate has different spectral features in comparison with its analogues due to the Jahn-Teller effect.