Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Vibrational spectroscopic investigations of M(Imidazole)2Ni(CN)4.2 Dioxane clathrates.
AU - Tufan, Yüksel
AU - Karacan, Nurcan
AU - Davies, J. Eric D.
PY - 1999/2
Y1 - 1999/2
N2 - Four new clathrates of the formula M(Im)2Ni(CN)4·2·Dioxane (where M = Co, Ni, Cu, Cd; Im = Imidazole) have been prepared in powder form and their FT-IR and laser-Raman spectra are reported for the first time. These clathrates are analogues to the previously reported classical Hofmann type clathrates except for the copper clathrate. The Cu clathrate has different spectral features in comparison with its analogues due to the Jahn-Teller effect.
AB - Four new clathrates of the formula M(Im)2Ni(CN)4·2·Dioxane (where M = Co, Ni, Cu, Cd; Im = Imidazole) have been prepared in powder form and their FT-IR and laser-Raman spectra are reported for the first time. These clathrates are analogues to the previously reported classical Hofmann type clathrates except for the copper clathrate. The Cu clathrate has different spectral features in comparison with its analogues due to the Jahn-Teller effect.
KW - Hofmann-type clathrate - metal-imidazole complexes - dioxane inclusion compounds - IR and Raman spectra
U2 - 10.1023/A:1007941906692
DO - 10.1023/A:1007941906692
M3 - Journal article
VL - 33
SP - 149
EP - 154
JO - Journal of Inclusion Phenomena and Macrocyclic Chemistry
JF - Journal of Inclusion Phenomena and Macrocyclic Chemistry
SN - 0923-0750
IS - 2
ER -