When indoles meet allene and its derivatives

Chemistry

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When indoles meet allene and its derivatives. / Alonso Gomez, José M.; Muñoz, María Paz.
In: European Journal of Organic Chemistry, Vol. 2020, No. 46, 22.10.2020, p. 7197-7213.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Alonso Gomez, JM & Muñoz, MP 2020, 'When indoles meet allene and its derivatives', European Journal of Organic Chemistry, vol. 2020, no. 46, pp. 7197-7213. https://doi.org/10.1002/ejoc.202001269

APA

Alonso Gomez, J. M., & Muñoz, M. P. (2020). When indoles meet allene and its derivatives. European Journal of Organic Chemistry, 2020(46), 7197-7213. https://doi.org/10.1002/ejoc.202001269

Vancouver

Alonso Gomez JM, Muñoz MP. When indoles meet allene and its derivatives. European Journal of Organic Chemistry. 2020 Oct 22;2020(46):7197-7213. doi: 10.1002/ejoc.202001269

Author

Alonso Gomez, José M. ; Muñoz, María Paz. / When indoles meet allene and its derivatives. In: European Journal of Organic Chemistry. 2020 ; Vol. 2020, No. 46. pp. 7197-7213.

Bibtex

@article{95fd6093866b4c59a058cb017a0d9eba,

title = "When indoles meet allene and its derivatives",

abstract = "The allene functional group and the indole ring have emerged as recurring building blocks in organic chemistry due to their diverse reactivity and straightforward preparation. In addition, the biological properties and natural occurrence of indole give a remarkable added-value to newly-prepared indole-based structures. In the last decade, the combination of allenes and indoles as co-reactants has revealed a fruitful reactivity allowing the synthesis of complex structures and the investigation of new mechanistic pathways, such as the challenging asymmetric nucleophilic addition using optically pure allenes as chirality transfer agents, the double nucleophilic addition through metal carbene intermediates, or novel hybrid catalysis in a bimetallic system. Herein we report a critical review into the wide and fascinating ways allenes and indoles can interact, and the structural diversity that can be therefore achieved.",

keywords = "allenes, insoles, transition metal, catalysis, polycyclic structures",

author = "{Alonso Gomez}, {Jos{\'e} M.} and Mu{\~n}oz, {Mar{\'i}a Paz}",

note = "Invited contribution for the Special issue called {"}your JOCTalents{"}",

year = "2020",

month = oct,

day = "22",

doi = "10.1002/ejoc.202001269",

language = "English",

volume = "2020",

pages = "7197--7213",

journal = "European Journal of Organic Chemistry",

issn = "1434-193X",

publisher = "Wiley-VCH Verlag",

number = "46",

}

RIS

TY - JOUR

T1 - When indoles meet allene and its derivatives

AU - Alonso Gomez, José M.

AU - Muñoz, María Paz

N1 - Invited contribution for the Special issue called "your JOCTalents"

PY - 2020/10/22

Y1 - 2020/10/22

N2 - The allene functional group and the indole ring have emerged as recurring building blocks in organic chemistry due to their diverse reactivity and straightforward preparation. In addition, the biological properties and natural occurrence of indole give a remarkable added-value to newly-prepared indole-based structures. In the last decade, the combination of allenes and indoles as co-reactants has revealed a fruitful reactivity allowing the synthesis of complex structures and the investigation of new mechanistic pathways, such as the challenging asymmetric nucleophilic addition using optically pure allenes as chirality transfer agents, the double nucleophilic addition through metal carbene intermediates, or novel hybrid catalysis in a bimetallic system. Herein we report a critical review into the wide and fascinating ways allenes and indoles can interact, and the structural diversity that can be therefore achieved.

AB - The allene functional group and the indole ring have emerged as recurring building blocks in organic chemistry due to their diverse reactivity and straightforward preparation. In addition, the biological properties and natural occurrence of indole give a remarkable added-value to newly-prepared indole-based structures. In the last decade, the combination of allenes and indoles as co-reactants has revealed a fruitful reactivity allowing the synthesis of complex structures and the investigation of new mechanistic pathways, such as the challenging asymmetric nucleophilic addition using optically pure allenes as chirality transfer agents, the double nucleophilic addition through metal carbene intermediates, or novel hybrid catalysis in a bimetallic system. Herein we report a critical review into the wide and fascinating ways allenes and indoles can interact, and the structural diversity that can be therefore achieved.

KW - allenes

KW - insoles

KW - transition metal

KW - catalysis

KW - polycyclic structures

U2 - 10.1002/ejoc.202001269

DO - 10.1002/ejoc.202001269

M3 - Journal article

VL - 2020

SP - 7197

EP - 7213

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

SN - 1434-193X

IS - 46

ER -

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