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Cobalt-Catalysed, Ligand-Controlled Regiodivergent Alkene Hydrosilylation

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Cobalt-Catalysed, Ligand-Controlled Regiodivergent Alkene Hydrosilylation. / Docherty, Jamie H.; Dominey, Andrew P.; Thomas, Stephen P.
In: Asian Journal of Organic Chemistry, Vol. 10, No. 9, 30.09.2021, p. 2379-2384.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Docherty, JH, Dominey, AP & Thomas, SP 2021, 'Cobalt-Catalysed, Ligand-Controlled Regiodivergent Alkene Hydrosilylation', Asian Journal of Organic Chemistry, vol. 10, no. 9, pp. 2379-2384. https://doi.org/10.1002/ajoc.202100361

APA

Docherty, J. H., Dominey, A. P., & Thomas, S. P. (2021). Cobalt-Catalysed, Ligand-Controlled Regiodivergent Alkene Hydrosilylation. Asian Journal of Organic Chemistry, 10(9), 2379-2384. https://doi.org/10.1002/ajoc.202100361

Vancouver

Docherty JH, Dominey AP, Thomas SP. Cobalt-Catalysed, Ligand-Controlled Regiodivergent Alkene Hydrosilylation. Asian Journal of Organic Chemistry. 2021 Sept 30;10(9):2379-2384. Epub 2021 Jul 27. doi: 10.1002/ajoc.202100361

Author

Docherty, Jamie H. ; Dominey, Andrew P. ; Thomas, Stephen P. / Cobalt-Catalysed, Ligand-Controlled Regiodivergent Alkene Hydrosilylation. In: Asian Journal of Organic Chemistry. 2021 ; Vol. 10, No. 9. pp. 2379-2384.

Bibtex

@article{827e2336fc504fa39dd39b6de676f7c9,
title = "Cobalt-Catalysed, Ligand-Controlled Regiodivergent Alkene Hydrosilylation",
abstract = "Alkene hydrosilylation is amongst the largest industrial homogenous catalysis processes. Cobalt catalysis offers a sustainable alternative to commonly used platinum catalysts to achieve this transformation. Using two bisiminopyridine cobalt(II) catalysts the regiodivergent hydrosilylation of alkenes has been developed. Variation of pre-catalyst activator and ligand substituents were investigated to enable the controlled, regiodivergent hydrosilylation of both aryl- and alkyl-substituted alkenes with phenylsilane. In contrast to other regiodivergence strategies, excellent regioselectivity for either isomer was achieved using the same ligand class but differing by a single methyl group (ethyl vs isopropyl).",
keywords = "Catalysis, Cobalt, Hydrosilylation, Silane, Silicon",
author = "Docherty, {Jamie H.} and Dominey, {Andrew P.} and Thomas, {Stephen P.}",
year = "2021",
month = sep,
day = "30",
doi = "10.1002/ajoc.202100361",
language = "English",
volume = "10",
pages = "2379--2384",
journal = "Asian Journal of Organic Chemistry",
issn = "2193-5807",
publisher = "Wiley - VCH Verlag GmbH & CO. KGaA",
number = "9",

}

RIS

TY - JOUR

T1 - Cobalt-Catalysed, Ligand-Controlled Regiodivergent Alkene Hydrosilylation

AU - Docherty, Jamie H.

AU - Dominey, Andrew P.

AU - Thomas, Stephen P.

PY - 2021/9/30

Y1 - 2021/9/30

N2 - Alkene hydrosilylation is amongst the largest industrial homogenous catalysis processes. Cobalt catalysis offers a sustainable alternative to commonly used platinum catalysts to achieve this transformation. Using two bisiminopyridine cobalt(II) catalysts the regiodivergent hydrosilylation of alkenes has been developed. Variation of pre-catalyst activator and ligand substituents were investigated to enable the controlled, regiodivergent hydrosilylation of both aryl- and alkyl-substituted alkenes with phenylsilane. In contrast to other regiodivergence strategies, excellent regioselectivity for either isomer was achieved using the same ligand class but differing by a single methyl group (ethyl vs isopropyl).

AB - Alkene hydrosilylation is amongst the largest industrial homogenous catalysis processes. Cobalt catalysis offers a sustainable alternative to commonly used platinum catalysts to achieve this transformation. Using two bisiminopyridine cobalt(II) catalysts the regiodivergent hydrosilylation of alkenes has been developed. Variation of pre-catalyst activator and ligand substituents were investigated to enable the controlled, regiodivergent hydrosilylation of both aryl- and alkyl-substituted alkenes with phenylsilane. In contrast to other regiodivergence strategies, excellent regioselectivity for either isomer was achieved using the same ligand class but differing by a single methyl group (ethyl vs isopropyl).

KW - Catalysis

KW - Cobalt

KW - Hydrosilylation

KW - Silane

KW - Silicon

U2 - 10.1002/ajoc.202100361

DO - 10.1002/ajoc.202100361

M3 - Journal article

AN - SCOPUS:85111945563

VL - 10

SP - 2379

EP - 2384

JO - Asian Journal of Organic Chemistry

JF - Asian Journal of Organic Chemistry

SN - 2193-5807

IS - 9

ER -