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Cross-conjugation increases the conductance of: Meta-connected fluorenones

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Cross-conjugation increases the conductance of: Meta-connected fluorenones. / Alanazy, Asma; Leary, E.; Kobatake, T. et al.
In: Nanoscale, Vol. 11, No. 29, 07.08.2019, p. 13720-13724.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Alanazy, A, Leary, E, Kobatake, T, Sangtarash, S, González, MT, Jiang, H-W, Bollinger, GR, Agräit, N, Sadeghi, H, Grace, I, Higgins, SJ, Anderson, HL, Nichols, RJ & Lambert, CJ 2019, 'Cross-conjugation increases the conductance of: Meta-connected fluorenones', Nanoscale, vol. 11, no. 29, pp. 13720-13724. https://doi.org/10.1039/c9nr01235d

APA

Alanazy, A., Leary, E., Kobatake, T., Sangtarash, S., González, M. T., Jiang, H.-W., Bollinger, G. R., Agräit, N., Sadeghi, H., Grace, I., Higgins, S. J., Anderson, H. L., Nichols, R. J., & Lambert, C. J. (2019). Cross-conjugation increases the conductance of: Meta-connected fluorenones. Nanoscale, 11(29), 13720-13724. https://doi.org/10.1039/c9nr01235d

Vancouver

Alanazy A, Leary E, Kobatake T, Sangtarash S, González MT, Jiang HW et al. Cross-conjugation increases the conductance of: Meta-connected fluorenones. Nanoscale. 2019 Aug 7;11(29):13720-13724. Epub 2019 Jul 12. doi: 10.1039/c9nr01235d

Author

Alanazy, Asma ; Leary, E. ; Kobatake, T. et al. / Cross-conjugation increases the conductance of : Meta-connected fluorenones. In: Nanoscale. 2019 ; Vol. 11, No. 29. pp. 13720-13724.

Bibtex

@article{3047849ebe684d619f5807a3ed066933,
title = "Cross-conjugation increases the conductance of: Meta-connected fluorenones",
abstract = "Charge transport is strongly suppressed by destructive quantum interference (DQI) in meta-connected 1,1′-biphenyl-containing molecules, resulting in low electrical conductance. Surprisingly, we have found that DQI is almost entirely overcome by adding a bridging carbonyl, to yield a cross-conjugated fluorenone. This contrasts with other π-systems, such as para-connected anthraquinone, where cross-conjugation results in low conductance.",
author = "Asma Alanazy and E. Leary and T. Kobatake and Sara Sangtarash and M.T. Gonz{\'a}lez and H.-W. Jiang and G.R. Bollinger and N. Agr{\"a}it and Hatef Sadeghi and Iain Grace and S.J. Higgins and H.L. Anderson and R.J. Nichols and Lambert, {Colin J.}",
year = "2019",
month = aug,
day = "7",
doi = "10.1039/c9nr01235d",
language = "English",
volume = "11",
pages = "13720--13724",
journal = "Nanoscale",
issn = "2040-3364",
publisher = "Royal Society of Chemistry",
number = "29",

}

RIS

TY - JOUR

T1 - Cross-conjugation increases the conductance of

T2 - Meta-connected fluorenones

AU - Alanazy, Asma

AU - Leary, E.

AU - Kobatake, T.

AU - Sangtarash, Sara

AU - González, M.T.

AU - Jiang, H.-W.

AU - Bollinger, G.R.

AU - Agräit, N.

AU - Sadeghi, Hatef

AU - Grace, Iain

AU - Higgins, S.J.

AU - Anderson, H.L.

AU - Nichols, R.J.

AU - Lambert, Colin J.

PY - 2019/8/7

Y1 - 2019/8/7

N2 - Charge transport is strongly suppressed by destructive quantum interference (DQI) in meta-connected 1,1′-biphenyl-containing molecules, resulting in low electrical conductance. Surprisingly, we have found that DQI is almost entirely overcome by adding a bridging carbonyl, to yield a cross-conjugated fluorenone. This contrasts with other π-systems, such as para-connected anthraquinone, where cross-conjugation results in low conductance.

AB - Charge transport is strongly suppressed by destructive quantum interference (DQI) in meta-connected 1,1′-biphenyl-containing molecules, resulting in low electrical conductance. Surprisingly, we have found that DQI is almost entirely overcome by adding a bridging carbonyl, to yield a cross-conjugated fluorenone. This contrasts with other π-systems, such as para-connected anthraquinone, where cross-conjugation results in low conductance.

U2 - 10.1039/c9nr01235d

DO - 10.1039/c9nr01235d

M3 - Journal article

VL - 11

SP - 13720

EP - 13724

JO - Nanoscale

JF - Nanoscale

SN - 2040-3364

IS - 29

ER -