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Research output: Contribution in Book/Report/Proceedings - With ISBN/ISSN › Conference contribution/Paper › peer-review
Research output: Contribution in Book/Report/Proceedings - With ISBN/ISSN › Conference contribution/Paper › peer-review
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TY - GEN
T1 - Predicting complex multi-species phase structure for ionic conduction in nanopores
AU - Gibby, William A. T.
AU - Barabash, Miraslau L.
AU - Luchinsky, Dmitry G.
AU - McClintock, Peter V. E.
AU - Khovanov, Igor A.
PY - 2024/3/25
Y1 - 2024/3/25
N2 - Using a statistical linear response theory, we present a complex phase structure describing ionic conduction through a nanopore as a function of pore structure. This picture sheds light on the permeation mechanism, and selectivity between ions of alike and differing charge; and is calculated explicitly from first principles via the statistical properties including particle number fluctuations. We therefore expect the theory to be applicable to the functionalisation and design of highly selective nanopores.
AB - Using a statistical linear response theory, we present a complex phase structure describing ionic conduction through a nanopore as a function of pore structure. This picture sheds light on the permeation mechanism, and selectivity between ions of alike and differing charge; and is calculated explicitly from first principles via the statistical properties including particle number fluctuations. We therefore expect the theory to be applicable to the functionalisation and design of highly selective nanopores.
KW - selective conduction, ionic Coulomb blockade, resonant conduction
U2 - 10.1109/ICNF57520.2023.10472760
DO - 10.1109/ICNF57520.2023.10472760
M3 - Conference contribution/Paper
SN - 9798350330120
BT - 2023 International Conference on Noise and Fluctuations (ICNF)
PB - IEEE
ER -