Research output: Contribution to Journal/Magazine › Journal article › peer-review
| Article number | 131084 |
|---|---|
| <mark>Journal publication date</mark> | 10/04/2020 |
| <mark>Journal</mark> | Tetrahedron |
| Issue number | 15 |
| Volume | 76 |
| Publication Status | Published |
| <mark>Original language</mark> | English |
The synthesis of DBpin was achieved using (EtBIP)CoCl2 or (tBuPNN)FeCl2 as pre-catalysts activated with NaOtBu. (EtBIP)CoCl2 was used as a pre-catalyst for the hydrogen isotope exchange of HBpin with D2, and (tBuPNN)FeCl2 for deuterogenolysis of B2pin2. The one-pot, tandem hydrogenolysis-hydroboration/deuterogenolysis-deuteroboration reaction of terminal alkenes could be catalysed by (tBuPNN)FeCl2 to give alkyl boronic esters.