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Synthesis of DBpin using Earth-abundant metal catalysis

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Synthesis of DBpin using Earth-abundant metal catalysis. / Cummins, Andrew W.M.; Li, Shuyang; Willcox, Dominic R. et al.
In: Tetrahedron, Vol. 76, No. 15, 131084, 10.04.2020.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Cummins, AWM, Li, S, Willcox, DR, Muilu, T, Docherty, JH & Thomas, SP 2020, 'Synthesis of DBpin using Earth-abundant metal catalysis', Tetrahedron, vol. 76, no. 15, 131084. https://doi.org/10.1016/j.tet.2020.131084

APA

Cummins, A. W. M., Li, S., Willcox, D. R., Muilu, T., Docherty, J. H., & Thomas, S. P. (2020). Synthesis of DBpin using Earth-abundant metal catalysis. Tetrahedron, 76(15), Article 131084. https://doi.org/10.1016/j.tet.2020.131084

Vancouver

Cummins AWM, Li S, Willcox DR, Muilu T, Docherty JH, Thomas SP. Synthesis of DBpin using Earth-abundant metal catalysis. Tetrahedron. 2020 Apr 10;76(15):131084. doi: 10.1016/j.tet.2020.131084

Author

Cummins, Andrew W.M. ; Li, Shuyang ; Willcox, Dominic R. et al. / Synthesis of DBpin using Earth-abundant metal catalysis. In: Tetrahedron. 2020 ; Vol. 76, No. 15.

Bibtex

@article{d701d08b123748369b416015ceadb8e8,
title = "Synthesis of DBpin using Earth-abundant metal catalysis",
abstract = "The synthesis of DBpin was achieved using (EtBIP)CoCl2 or (tBuPNN)FeCl2 as pre-catalysts activated with NaOtBu. (EtBIP)CoCl2 was used as a pre-catalyst for the hydrogen isotope exchange of HBpin with D2, and (tBuPNN)FeCl2 for deuterogenolysis of B2pin2. The one-pot, tandem hydrogenolysis-hydroboration/deuterogenolysis-deuteroboration reaction of terminal alkenes could be catalysed by (tBuPNN)FeCl2 to give alkyl boronic esters.",
keywords = "Boron, Catalysis, Cobalt, Deuterium, Iron",
author = "Cummins, {Andrew W.M.} and Shuyang Li and Willcox, {Dominic R.} and Tommi Muilu and Docherty, {Jamie H.} and Thomas, {Stephen P.}",
year = "2020",
month = apr,
day = "10",
doi = "10.1016/j.tet.2020.131084",
language = "English",
volume = "76",
journal = "Tetrahedron",
issn = "0040-4020",
publisher = "Elsevier Limited",
number = "15",

}

RIS

TY - JOUR

T1 - Synthesis of DBpin using Earth-abundant metal catalysis

AU - Cummins, Andrew W.M.

AU - Li, Shuyang

AU - Willcox, Dominic R.

AU - Muilu, Tommi

AU - Docherty, Jamie H.

AU - Thomas, Stephen P.

PY - 2020/4/10

Y1 - 2020/4/10

N2 - The synthesis of DBpin was achieved using (EtBIP)CoCl2 or (tBuPNN)FeCl2 as pre-catalysts activated with NaOtBu. (EtBIP)CoCl2 was used as a pre-catalyst for the hydrogen isotope exchange of HBpin with D2, and (tBuPNN)FeCl2 for deuterogenolysis of B2pin2. The one-pot, tandem hydrogenolysis-hydroboration/deuterogenolysis-deuteroboration reaction of terminal alkenes could be catalysed by (tBuPNN)FeCl2 to give alkyl boronic esters.

AB - The synthesis of DBpin was achieved using (EtBIP)CoCl2 or (tBuPNN)FeCl2 as pre-catalysts activated with NaOtBu. (EtBIP)CoCl2 was used as a pre-catalyst for the hydrogen isotope exchange of HBpin with D2, and (tBuPNN)FeCl2 for deuterogenolysis of B2pin2. The one-pot, tandem hydrogenolysis-hydroboration/deuterogenolysis-deuteroboration reaction of terminal alkenes could be catalysed by (tBuPNN)FeCl2 to give alkyl boronic esters.

KW - Boron

KW - Catalysis

KW - Cobalt

KW - Deuterium

KW - Iron

UR - http://www.scopus.com/inward/record.url?scp=85081026457&partnerID=8YFLogxK

U2 - 10.1016/j.tet.2020.131084

DO - 10.1016/j.tet.2020.131084

M3 - Journal article

AN - SCOPUS:85081026457

VL - 76

JO - Tetrahedron

JF - Tetrahedron

SN - 0040-4020

IS - 15

M1 - 131084

ER -