Home > Research > Publications & Outputs > Thermodynamics of stationary states of the idea...

Electronic data

  • 2111.13095

    Rights statement: Copyright 2022 American Institute of Physics. The following article appeared in Journal of Chemical Physics, 157 (19), 2022 and may be found at http://dx.doi.org/10.1063/5.0128074 This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.

    Accepted author manuscript, 648 KB, PDF document

    Available under license: CC BY: Creative Commons Attribution 4.0 International License

Links

Text available via DOI:

View graph of relations

Thermodynamics of stationary states of the ideal gas in a heat flow

Research output: Contribution to Journal/MagazineJournal articlepeer-review

Published
  • Karol Makuch
  • Robert Hołyst
  • Anna Maciołek
  • Pawel Zuk
Close
<mark>Journal publication date</mark>21/11/2022
<mark>Journal</mark>Journal of Chemical Physics
Issue number19
Volume157
Publication StatusPublished
<mark>Original language</mark>English

Abstract

There is a long-standing question as to whether and to what extent it is possible to describe nonequilibrium systems in stationary states in terms of global thermodynamic functions. The positive answers have been obtained only for isothermal systems or systems with small temperature differences. We formulate thermodynamics of the stationary states of the ideal gas subjected to heat flow in the form of the zeroth, first, and second law. Surprisingly, the formal structure of steady state thermodynamics is the same as in equilibrium thermodynamics. We rigorously show that U satisfies the following equation dU= T* dS* -pdV for a constant number of particles, irrespective of the shape of the container, boundary conditions, size of the system, or mode of heat transfer into the system. We calculate S* and T* explicitly. The theory selects stable nonequilibrium steady states in a multistable system of ideal gas subjected to volumetric heating. It reduces to equilibrium thermodynamics when heat flux goes to zero.

Bibliographic note

Copyright 2022 American Institute of Physics. The following article appeared in Journal of Chemical Physics, 157 (19), 2022 and may be found at http://dx.doi.org/10.1063/5.0128074 This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.