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  • Acta Cryst. (2017). E73 842

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trans-Di-chlorido-bis-(dimethyl sulfoxide-κO)bis-(4-fluoro-benzyl-κC(1))tin(IV): crystal structure and Hirshfeld surface analysis

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  • Nur Adibah Binti Mohd Amin
  • Rusnah Syahila Duali Hussen
  • See Mun Lee
  • Nathan R. Halcovitch
  • Mukesh M. Jotani
  • Edward R. T. Tiekink
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<mark>Journal publication date</mark>1/05/2017
<mark>Journal</mark>Acta crystallographica. Section E, Crystallographic communications
Issue numberPt 5
Volume73
Number of pages6
Pages (from-to)667-672
Publication StatusPublished
<mark>Original language</mark>English

Abstract

The Sn(IV) atom in the title diorganotin compound, [Sn(C7H6F)2Cl2(C2H6OS)2], is located on a centre of inversion, resulting in the C2Cl2O2 donor set having an all-trans disposition of like atoms. The coordination geometry approximates an octa-hedron. The crystal features C-H⋯F, C-H⋯Cl and C-H⋯π inter-actions, giving rise to a three-dimensional network. The respective influences of the Cl⋯H/H⋯Cl and F⋯H/H⋯F contacts to the mol-ecular packing are clearly evident from the analysis of the Hirshfeld surface.