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Final published version
Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - trans-Di-chlorido-bis-(dimethyl sulfoxide-κO)bis-(4-fluoro-benzyl-κC(1))tin(IV)
T2 - crystal structure and Hirshfeld surface analysis
AU - Amin, Nur Adibah Binti Mohd
AU - Hussen, Rusnah Syahila Duali
AU - Lee, See Mun
AU - Halcovitch, Nathan R.
AU - Jotani, Mukesh M.
AU - Tiekink, Edward R. T.
PY - 2017/5/1
Y1 - 2017/5/1
N2 - The Sn(IV) atom in the title diorganotin compound, [Sn(C7H6F)2Cl2(C2H6OS)2], is located on a centre of inversion, resulting in the C2Cl2O2 donor set having an all-trans disposition of like atoms. The coordination geometry approximates an octa-hedron. The crystal features C-H⋯F, C-H⋯Cl and C-H⋯π inter-actions, giving rise to a three-dimensional network. The respective influences of the Cl⋯H/H⋯Cl and F⋯H/H⋯F contacts to the mol-ecular packing are clearly evident from the analysis of the Hirshfeld surface.
AB - The Sn(IV) atom in the title diorganotin compound, [Sn(C7H6F)2Cl2(C2H6OS)2], is located on a centre of inversion, resulting in the C2Cl2O2 donor set having an all-trans disposition of like atoms. The coordination geometry approximates an octa-hedron. The crystal features C-H⋯F, C-H⋯Cl and C-H⋯π inter-actions, giving rise to a three-dimensional network. The respective influences of the Cl⋯H/H⋯Cl and F⋯H/H⋯F contacts to the mol-ecular packing are clearly evident from the analysis of the Hirshfeld surface.
KW - Journal Article
U2 - 10.1107/S2056989017005072
DO - 10.1107/S2056989017005072
M3 - Journal article
C2 - 28529772
VL - 73
SP - 667
EP - 672
JO - Acta crystallographica. Section E, Crystallographic communications
JF - Acta crystallographica. Section E, Crystallographic communications
SN - 2056-9890
IS - Pt 5
ER -